Synthesis, characterization and molecular structure of the [(η6-C6Me6)Ru(μ-N3) (N3)]2 complex and its reactions with some monodentate ligands

P. Govindaswamy; Hemant P. Yennawar; Mohan Rao Kollipara

doi:10.1016/j.jorganchem.2004.06.034

Synthesis, characterization and molecular structure of the [(η⁶-C₆Me₆)Ru(μ-N₃) (N₃)]₂ complex and its reactions with some monodentate ligands

P. Govindaswamy, Hemant P. Yennawar, Mohan Rao Kollipara

Biochemistry & Molecular Biology

Research output: Contribution to journal › Short survey › peer-review

25 Scopus citations

Abstract

The reaction of complex [(η⁶-C₆Me₆) Ru(μ-Cl)Cl]₂ (1) with sodium azide yielded complexes of the composition [(η⁶-C₆Me₆) Ru(μ-N₃)(N₃)]₂ (2) and [(η⁶-C₆Me₆)Ru(μ-N₃) (Cl)]₂ (3), depending upon the reaction conditions. Complex 3 with excess of sodium azide in ethanol yielded complex 2 . Complexes 2 and 3 undergo substitution reactions with monodentate ligands such as PPh₃, PMe₂Ph and AsPh₃ to yield monomeric complexes. The structure of complex 2 was determined by X-ray crystallography. All these complexes were characterized by micro analytical data and by FT-IR and FT-NMR spectroscopy. Complex 2 crystallizes in the monoclinic space group P2_1n with a = 8.5370(11) Å, b = 16.192(2) Å, c = 10.4535(13) Å and β = 110.877(2)°.

Original language	English (US)
Pages (from-to)	3108-3112
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	689
Issue number	19
DOIs	https://doi.org/10.1016/j.jorganchem.2004.06.034
State	Published - Sep 22 2004

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2004.06.034

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@article{af546d1853d64fc9a8941f1aef2d0a05,

title = "Synthesis, characterization and molecular structure of the [(η6-C6Me6)Ru(μ-N3) (N3)]2 complex and its reactions with some monodentate ligands",

abstract = "The reaction of complex [(η6-C6Me6) Ru(μ-Cl)Cl]2 (1) with sodium azide yielded complexes of the composition [(η6-C6Me6) Ru(μ-N3)(N3)]2 (2) and [(η6-C6Me6)Ru(μ-N3) (Cl)]2 (3), depending upon the reaction conditions. Complex 3 with excess of sodium azide in ethanol yielded complex 2 . Complexes 2 and 3 undergo substitution reactions with monodentate ligands such as PPh3, PMe2Ph and AsPh3 to yield monomeric complexes. The structure of complex 2 was determined by X-ray crystallography. All these complexes were characterized by micro analytical data and by FT-IR and FT-NMR spectroscopy. Complex 2 crystallizes in the monoclinic space group P21n with a = 8.5370(11) {\AA}, b = 16.192(2) {\AA}, c = 10.4535(13) {\AA} and β = 110.877(2)°.",

author = "P. Govindaswamy and Yennawar, {Hemant P.} and Kollipara, {Mohan Rao}",

note = "Funding Information: H.P.Y. acknowledges NSF grant CHE-0131112 for the purchase of the diffractometer. ",

year = "2004",

month = sep,

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doi = "10.1016/j.jorganchem.2004.06.034",

language = "English (US)",

volume = "689",

pages = "3108--3112",

journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Synthesis, characterization and molecular structure of the [(η6-C6Me6)Ru(μ-N3) (N3)]2 complex and its reactions with some monodentate ligands

AU - Govindaswamy, P.

AU - Yennawar, Hemant P.

AU - Kollipara, Mohan Rao

N1 - Funding Information: H.P.Y. acknowledges NSF grant CHE-0131112 for the purchase of the diffractometer.

PY - 2004/9/22

Y1 - 2004/9/22

N2 - The reaction of complex [(η6-C6Me6) Ru(μ-Cl)Cl]2 (1) with sodium azide yielded complexes of the composition [(η6-C6Me6) Ru(μ-N3)(N3)]2 (2) and [(η6-C6Me6)Ru(μ-N3) (Cl)]2 (3), depending upon the reaction conditions. Complex 3 with excess of sodium azide in ethanol yielded complex 2 . Complexes 2 and 3 undergo substitution reactions with monodentate ligands such as PPh3, PMe2Ph and AsPh3 to yield monomeric complexes. The structure of complex 2 was determined by X-ray crystallography. All these complexes were characterized by micro analytical data and by FT-IR and FT-NMR spectroscopy. Complex 2 crystallizes in the monoclinic space group P21n with a = 8.5370(11) Å, b = 16.192(2) Å, c = 10.4535(13) Å and β = 110.877(2)°.

AB - The reaction of complex [(η6-C6Me6) Ru(μ-Cl)Cl]2 (1) with sodium azide yielded complexes of the composition [(η6-C6Me6) Ru(μ-N3)(N3)]2 (2) and [(η6-C6Me6)Ru(μ-N3) (Cl)]2 (3), depending upon the reaction conditions. Complex 3 with excess of sodium azide in ethanol yielded complex 2 . Complexes 2 and 3 undergo substitution reactions with monodentate ligands such as PPh3, PMe2Ph and AsPh3 to yield monomeric complexes. The structure of complex 2 was determined by X-ray crystallography. All these complexes were characterized by micro analytical data and by FT-IR and FT-NMR spectroscopy. Complex 2 crystallizes in the monoclinic space group P21n with a = 8.5370(11) Å, b = 16.192(2) Å, c = 10.4535(13) Å and β = 110.877(2)°.

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U2 - 10.1016/j.jorganchem.2004.06.034

DO - 10.1016/j.jorganchem.2004.06.034

M3 - Short survey

AN - SCOPUS:4444258763

SN - 0022-328X

VL - 689

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EP - 3112

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 19

ER -

Synthesis, characterization and molecular structure of the [(η⁶-C₆Me₆)Ru(μ-N₃) (N₃)]₂ complex and its reactions with some monodentate ligands

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