Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes

Naomi Basickes; Alan C. Hutson; Ayusman Sen; Glen P.A. Yap; Arnold L. Rheingold

doi:10.1021/om960495u

Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes

Naomi Basickes, Alan C. Hutson, Ayusman Sen, Glen P.A. Yap, Arnold L. Rheingold

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A new Pt(II) ethyl ethene complex, [Pt(μ-Cl)-(CH₂CH₃)(C₂H₄] ₂, (1), was isolated from the reaction of ethene with K₂PtCl₄ in water, and the structure was confirmed by X-ray crystallography. The results of oxidation experiments involving 1 indicate that Pt^II-C₂H₅ and Pt^II-(CH₂=CH₂) species are viable intermediates in the conversion of ethane to ethanol and ethane-1,2-diol by the Shilov system.

Original language	English (US)
Pages (from-to)	4116-4118
Number of pages	3
Journal	Organometallics
Volume	15
Issue number	20
DOIs	https://doi.org/10.1021/om960495u
State	Published - Oct 1 1996

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes",

abstract = "A new Pt(II) ethyl ethene complex, [Pt(μ-Cl)-(CH2CH3)(C2H4] 2, (1), was isolated from the reaction of ethene with K2PtCl4 in water, and the structure was confirmed by X-ray crystallography. The results of oxidation experiments involving 1 indicate that PtII-C2H5 and PtII-(CH2=CH2) species are viable intermediates in the conversion of ethane to ethanol and ethane-1,2-diol by the Shilov system.",

author = "Naomi Basickes and Hutson, {Alan C.} and Ayusman Sen and Yap, {Glen P.A.} and Rheingold, {Arnold L.}",

year = "1996",

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T1 - Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes

AU - Basickes, Naomi

AU - Hutson, Alan C.

AU - Sen, Ayusman

AU - Yap, Glen P.A.

AU - Rheingold, Arnold L.

PY - 1996/10/1

Y1 - 1996/10/1

N2 - A new Pt(II) ethyl ethene complex, [Pt(μ-Cl)-(CH2CH3)(C2H4] 2, (1), was isolated from the reaction of ethene with K2PtCl4 in water, and the structure was confirmed by X-ray crystallography. The results of oxidation experiments involving 1 indicate that PtII-C2H5 and PtII-(CH2=CH2) species are viable intermediates in the conversion of ethane to ethanol and ethane-1,2-diol by the Shilov system.

AB - A new Pt(II) ethyl ethene complex, [Pt(μ-Cl)-(CH2CH3)(C2H4] 2, (1), was isolated from the reaction of ethene with K2PtCl4 in water, and the structure was confirmed by X-ray crystallography. The results of oxidation experiments involving 1 indicate that PtII-C2H5 and PtII-(CH2=CH2) species are viable intermediates in the conversion of ethane to ethanol and ethane-1,2-diol by the Shilov system.

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DO - 10.1021/om960495u

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JO - Organometallics

JF - Organometallics

IS - 20

ER -

Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes

Abstract

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