Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

Ajay A. Sathe; Anirudh M.K. Nambiar; Robert M. Rioux

doi:10.1039/c6cy01974a

Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

Ajay A. Sathe, Anirudh M.K. Nambiar, Robert M. Rioux

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Methodology for direct catalytic conversion of olefins into cyclic carbonates using peroxide and carbon dioxide under relatively mild conditions is demonstrated. The protocol utilizes packed bed flow reactors in series to couple rhenium catalyzed olefin epoxidation and aluminum catalyzed epoxide carboxylation in a single sequence.

Original language	English (US)
Pages (from-to)	84-89
Number of pages	6
Journal	Catalysis Science and Technology
Volume	7
Issue number	1
DOIs	https://doi.org/10.1039/c6cy01974a
State	Published - 2017

All Science Journal Classification (ASJC) codes

Catalysis

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10.1039/c6cy01974a

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title = "Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors",

abstract = "Methodology for direct catalytic conversion of olefins into cyclic carbonates using peroxide and carbon dioxide under relatively mild conditions is demonstrated. The protocol utilizes packed bed flow reactors in series to couple rhenium catalyzed olefin epoxidation and aluminum catalyzed epoxide carboxylation in a single sequence.",

author = "Sathe, {Ajay A.} and Nambiar, {Anirudh M.K.} and Rioux, {Robert M.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2017.",

year = "2017",

doi = "10.1039/c6cy01974a",

language = "English (US)",

volume = "7",

pages = "84--89",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

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T1 - Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

AU - Sathe, Ajay A.

AU - Nambiar, Anirudh M.K.

AU - Rioux, Robert M.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2017.

PY - 2017

Y1 - 2017

N2 - Methodology for direct catalytic conversion of olefins into cyclic carbonates using peroxide and carbon dioxide under relatively mild conditions is demonstrated. The protocol utilizes packed bed flow reactors in series to couple rhenium catalyzed olefin epoxidation and aluminum catalyzed epoxide carboxylation in a single sequence.

AB - Methodology for direct catalytic conversion of olefins into cyclic carbonates using peroxide and carbon dioxide under relatively mild conditions is demonstrated. The protocol utilizes packed bed flow reactors in series to couple rhenium catalyzed olefin epoxidation and aluminum catalyzed epoxide carboxylation in a single sequence.

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U2 - 10.1039/c6cy01974a

DO - 10.1039/c6cy01974a

M3 - Article

AN - SCOPUS:85008970242

SN - 2044-4753

VL - 7

SP - 84

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JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 1

ER -

Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

Abstract

All Science Journal Classification (ASJC) codes

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