Synthesis of (Hg,X)Ba2Ca2Cu3Ox superconductors

P. V.P.S.S. Sastry; K. M. Amm; D. C. Knoll; S. C. Peterson; Ch Wolters; J. Schwartz

doi:10.1023/A:1022673610947

Synthesis of (Hg,X)Ba₂Ca₂Cu₃O_x superconductors

P. V.P.S.S. Sastry
, K. M. Amm
, D. C. Knoll
, S. C. Peterson
, Ch Wolters
, J. Schwartz

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Synthesis and processing parameters for (Hg_1-xBi_x)Ba₂Ca₂Cu _3.1O_y were optimized for growth at temperatures suitable for growth on Ag and Au substrates (<850°C). Use of Bi₂CuO₄ as a Bi source combined with variations of BaCaCuO precursor phase assemblages allowed the formation of some liquid phase during the reaction and resulted in dense (Hg_1-xBi_x)Ba₂Ca₂Cu _3.1O_y samples with aligned colonies of grains. Magnetization measurements in fields up to 30 T indicated good intergrain coupling within the large grain colonies. The results of the Bi doped samples are compared with those of previously reported Re doped samples.

Original language	English (US)
Pages (from-to)	49-52
Number of pages	4
Journal	Journal of Superconductivity
Volume	11
Issue number	1
DOIs	https://doi.org/10.1023/A:1022673610947
State	Published - 1998

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Physics and Astronomy (miscellaneous)

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title = "Synthesis of (Hg,X)Ba2Ca2Cu3Ox superconductors",

abstract = "Synthesis and processing parameters for (Hg1-xBix)Ba2Ca2Cu 3.1Oy were optimized for growth at temperatures suitable for growth on Ag and Au substrates (<850°C). Use of Bi2CuO4 as a Bi source combined with variations of BaCaCuO precursor phase assemblages allowed the formation of some liquid phase during the reaction and resulted in dense (Hg1-xBix)Ba2Ca2Cu 3.1Oy samples with aligned colonies of grains. Magnetization measurements in fields up to 30 T indicated good intergrain coupling within the large grain colonies. The results of the Bi doped samples are compared with those of previously reported Re doped samples.",

author = "Sastry, \{P. V.P.S.S.\} and Amm, \{K. M.\} and Knoll, \{D. C.\} and Peterson, \{S. C.\} and Ch Wolters and J. Schwartz",

note = "Funding Information: This work was funded by the National Science Foundation under Grant No. DMR-9526231.",

year = "1998",

doi = "10.1023/A:1022673610947",

language = "English (US)",

volume = "11",

pages = "49--52",

journal = "Journal of Superconductivity",

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TY - JOUR

T1 - Synthesis of (Hg,X)Ba2Ca2Cu3Ox superconductors

AU - Sastry, P. V.P.S.S.

AU - Amm, K. M.

AU - Knoll, D. C.

AU - Peterson, S. C.

AU - Wolters, Ch

AU - Schwartz, J.

N1 - Funding Information: This work was funded by the National Science Foundation under Grant No. DMR-9526231.

PY - 1998

Y1 - 1998

N2 - Synthesis and processing parameters for (Hg1-xBix)Ba2Ca2Cu 3.1Oy were optimized for growth at temperatures suitable for growth on Ag and Au substrates (<850°C). Use of Bi2CuO4 as a Bi source combined with variations of BaCaCuO precursor phase assemblages allowed the formation of some liquid phase during the reaction and resulted in dense (Hg1-xBix)Ba2Ca2Cu 3.1Oy samples with aligned colonies of grains. Magnetization measurements in fields up to 30 T indicated good intergrain coupling within the large grain colonies. The results of the Bi doped samples are compared with those of previously reported Re doped samples.

AB - Synthesis and processing parameters for (Hg1-xBix)Ba2Ca2Cu 3.1Oy were optimized for growth at temperatures suitable for growth on Ag and Au substrates (<850°C). Use of Bi2CuO4 as a Bi source combined with variations of BaCaCuO precursor phase assemblages allowed the formation of some liquid phase during the reaction and resulted in dense (Hg1-xBix)Ba2Ca2Cu 3.1Oy samples with aligned colonies of grains. Magnetization measurements in fields up to 30 T indicated good intergrain coupling within the large grain colonies. The results of the Bi doped samples are compared with those of previously reported Re doped samples.

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DO - 10.1023/A:1022673610947

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Synthesis of (Hg,X)Ba₂Ca₂Cu₃O_x superconductors

Abstract

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