TY - JOUR
T1 - Synthesis of lipophilic N-phosphorylmethylated amino acids and their membrane-transport properties towards some organic acids
AU - Cherkasov, Rafael A.
AU - Koshkin, Sergey A.
AU - Garifzyanov, Airat R.
AU - Davletshina, Natal'ya V.
N1 - Publisher Copyright:
© 2016 Taylor & Francis Group, LLC.
PY - 2016/12/1
Y1 - 2016/12/1
N2 - One-pot procedureswere developed for the synthesis of lipophilic N-(dialkylphosphorylmethyl) derivatives of natural amino acids with high yields from dioctyloxide, formaldehyde, and an amino acid in the presence of amino acid hydrochloride.Membrane transport properties of the new phosphorylated amino acids towards polyfunctional carboxylic acidswere studied. Itwas found that N,N-bis[(dioctylphosphoryl)methyl]- β-alanine is a selective extractant for glutaric acid.
AB - One-pot procedureswere developed for the synthesis of lipophilic N-(dialkylphosphorylmethyl) derivatives of natural amino acids with high yields from dioctyloxide, formaldehyde, and an amino acid in the presence of amino acid hydrochloride.Membrane transport properties of the new phosphorylated amino acids towards polyfunctional carboxylic acidswere studied. Itwas found that N,N-bis[(dioctylphosphoryl)methyl]- β-alanine is a selective extractant for glutaric acid.
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U2 - 10.1080/10426507.2016.1223666
DO - 10.1080/10426507.2016.1223666
M3 - Article
AN - SCOPUS:84992618574
SN - 1042-6507
VL - 191
SP - 1650
EP - 1651
JO - Phosphorus, Sulfur and Silicon and the Related Elements
JF - Phosphorus, Sulfur and Silicon and the Related Elements
IS - 11-12
ER -