Synthesis of phase-pure orthorhombic YB2Cu3Ox under low oxygen pressure

U. Balachandran; R. B. Poeppel; J. E. Emerson; S. A. Johnson; M. T. Lanagan; C. A. Youngdahl; Shi Donglu; K. C. Goretta; N. G. Eror

doi:10.1016/0167-577X(89)90029-3

Synthesis of phase-pure orthorhombic YB₂Cu₃O_x under low oxygen pressure

U. Balachandran
, R. B. Poeppel
, J. E. Emerson
, S. A. Johnson
, M. T. Lanagan
, C. A. Youngdahl
, Shi Donglu
, K. C. Goretta
, N. G. Eror

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

Reaction of Y₂O₃, BaCO₃ and CuO for 4 h at 800°C in flowing O₂ with a total pressure of about 2.7×10²Pa, followed by cooling in O₂ at ambient pressure, has produced phase-pure orthorhombic YBa₂Cu₃O_x. Keeping the ratio of O₂ to evolved CO₂ above 50 was necessary to ensure phase purity. The resultant powder yielded pressed and sintered pellets with improved super-conducting properties.

Original language	English (US)
Pages (from-to)	454-456
Number of pages	3
Journal	Materials Letters
Volume	8
Issue number	11-12
DOIs	https://doi.org/10.1016/0167-577X(89)90029-3
State	Published - Nov 1989

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1016/0167-577X(89)90029-3

Cite this

@article{857816fc28464877adbd8cfdb86dc78d,

title = "Synthesis of phase-pure orthorhombic YB2Cu3Ox under low oxygen pressure",

abstract = "Reaction of Y2O3, BaCO3 and CuO for 4 h at 800°C in flowing O2 with a total pressure of about 2.7×102Pa, followed by cooling in O2 at ambient pressure, has produced phase-pure orthorhombic YBa2Cu3Ox. Keeping the ratio of O2 to evolved CO2 above 50 was necessary to ensure phase purity. The resultant powder yielded pressed and sintered pellets with improved super-conducting properties.",

author = "U. Balachandran and Poeppel, \{R. B.\} and Emerson, \{J. E.\} and Johnson, \{S. A.\} and Lanagan, \{M. T.\} and Youngdahl, \{C. A.\} and Shi Donglu and Goretta, \{K. C.\} and Eror, \{N. G.\}",

note = "Funding Information: The authors thank Ming Xu for measuring superconducting properties. This work was supported by the U.S. Department of Energy, Offices of Energy Storagea nd Distribution, Conservation and Renewable Energy, and Basic Energy Sciences, Materials Science, under contract number W-3 I-109-Eng-38.",

year = "1989",

month = nov,

doi = "10.1016/0167-577X(89)90029-3",

language = "English (US)",

volume = "8",

pages = "454--456",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier B.V.",

number = "11-12",

}

TY - JOUR

T1 - Synthesis of phase-pure orthorhombic YB2Cu3Ox under low oxygen pressure

AU - Balachandran, U.

AU - Poeppel, R. B.

AU - Emerson, J. E.

AU - Johnson, S. A.

AU - Lanagan, M. T.

AU - Youngdahl, C. A.

AU - Donglu, Shi

AU - Goretta, K. C.

AU - Eror, N. G.

N1 - Funding Information: The authors thank Ming Xu for measuring superconducting properties. This work was supported by the U.S. Department of Energy, Offices of Energy Storagea nd Distribution, Conservation and Renewable Energy, and Basic Energy Sciences, Materials Science, under contract number W-3 I-109-Eng-38.

PY - 1989/11

Y1 - 1989/11

N2 - Reaction of Y2O3, BaCO3 and CuO for 4 h at 800°C in flowing O2 with a total pressure of about 2.7×102Pa, followed by cooling in O2 at ambient pressure, has produced phase-pure orthorhombic YBa2Cu3Ox. Keeping the ratio of O2 to evolved CO2 above 50 was necessary to ensure phase purity. The resultant powder yielded pressed and sintered pellets with improved super-conducting properties.

AB - Reaction of Y2O3, BaCO3 and CuO for 4 h at 800°C in flowing O2 with a total pressure of about 2.7×102Pa, followed by cooling in O2 at ambient pressure, has produced phase-pure orthorhombic YBa2Cu3Ox. Keeping the ratio of O2 to evolved CO2 above 50 was necessary to ensure phase purity. The resultant powder yielded pressed and sintered pellets with improved super-conducting properties.

UR - https://www.scopus.com/pages/publications/0024770468

UR - https://www.scopus.com/pages/publications/0024770468#tab=citedBy

U2 - 10.1016/0167-577X(89)90029-3

DO - 10.1016/0167-577X(89)90029-3

M3 - Article

AN - SCOPUS:0024770468

SN - 0167-577X

VL - 8

SP - 454

EP - 456

JO - Materials Letters

JF - Materials Letters

IS - 11-12

ER -

Synthesis of phase-pure orthorhombic YB₂Cu₃O_x under low oxygen pressure

Abstract

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