Synthesis of polyphosphazenes with ethyleneoxy-containing side groups: New solid electrolyte materials

Harry R. Allcock; Susan E. Kuharcik; Carey S. Reed; Mark E. Napierala

doi:10.1021/ma9514535

Synthesis of polyphosphazenes with ethyleneoxy-containing side groups: New solid electrolyte materials

Harry R. Allcock, Susan E. Kuharcik, Carey S. Reed, Mark E. Napierala

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89 Scopus citations

Abstract

A series of mixed-substituent poly(organophosphazenes) with ethyleneoxy side groups has been synthesized. These polymers possess multiple electron-donor coordination sites that can form complexes with metal salts and generate "solid electrolyte" behavior. The polymers were characterized by ³¹P, ¹H, and ¹³C NMR spectroscopy, gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and elemental analysis. All the mixed-substituent polymers have low glass transition temperatures, from -70 to -56 °C, as well as at least one melting transition. Several polymer - lithium triflate complexes were examined by impedance analysis. The maximum conductivities for these polymere ranged from 1.6 × 10^-6 to 3.9 × 10^-5 S cm^-1.

Original language	English (US)
Pages (from-to)	3384-3389
Number of pages	6
Journal	Macromolecules
Volume	29
Issue number	10
DOIs	https://doi.org/10.1021/ma9514535
State	Published - May 6 1996

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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title = "Synthesis of polyphosphazenes with ethyleneoxy-containing side groups: New solid electrolyte materials",

abstract = "A series of mixed-substituent poly(organophosphazenes) with ethyleneoxy side groups has been synthesized. These polymers possess multiple electron-donor coordination sites that can form complexes with metal salts and generate {"}solid electrolyte{"} behavior. The polymers were characterized by 31P, 1H, and 13C NMR spectroscopy, gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and elemental analysis. All the mixed-substituent polymers have low glass transition temperatures, from -70 to -56 °C, as well as at least one melting transition. Several polymer - lithium triflate complexes were examined by impedance analysis. The maximum conductivities for these polymere ranged from 1.6 × 10-6 to 3.9 × 10-5 S cm-1.",

author = "Allcock, {Harry R.} and Kuharcik, {Susan E.} and Reed, {Carey S.} and Napierala, {Mark E.}",

year = "1996",

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T1 - Synthesis of polyphosphazenes with ethyleneoxy-containing side groups

T2 - New solid electrolyte materials

AU - Allcock, Harry R.

AU - Kuharcik, Susan E.

AU - Reed, Carey S.

AU - Napierala, Mark E.

PY - 1996/5/6

Y1 - 1996/5/6

N2 - A series of mixed-substituent poly(organophosphazenes) with ethyleneoxy side groups has been synthesized. These polymers possess multiple electron-donor coordination sites that can form complexes with metal salts and generate "solid electrolyte" behavior. The polymers were characterized by 31P, 1H, and 13C NMR spectroscopy, gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and elemental analysis. All the mixed-substituent polymers have low glass transition temperatures, from -70 to -56 °C, as well as at least one melting transition. Several polymer - lithium triflate complexes were examined by impedance analysis. The maximum conductivities for these polymere ranged from 1.6 × 10-6 to 3.9 × 10-5 S cm-1.

AB - A series of mixed-substituent poly(organophosphazenes) with ethyleneoxy side groups has been synthesized. These polymers possess multiple electron-donor coordination sites that can form complexes with metal salts and generate "solid electrolyte" behavior. The polymers were characterized by 31P, 1H, and 13C NMR spectroscopy, gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and elemental analysis. All the mixed-substituent polymers have low glass transition temperatures, from -70 to -56 °C, as well as at least one melting transition. Several polymer - lithium triflate complexes were examined by impedance analysis. The maximum conductivities for these polymere ranged from 1.6 × 10-6 to 3.9 × 10-5 S cm-1.

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Synthesis of polyphosphazenes with ethyleneoxy-containing side groups: New solid electrolyte materials

Abstract

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