Synthesis of polyphosphazenes with sulfonimide side groups

Michael A. Hofmann; Catherine M. Ambler; Andrew E. Maher; Elena Chalkova; Xiangyang Y. Zhou; Serguei N. Lvov; Harry R. Allcock

doi:10.1021/ma020330z

Synthesis of polyphosphazenes with sulfonimide side groups

Michael A. Hofmann
, Catherine M. Ambler
, Andrew E. Maher
, Elena Chalkova
, Xiangyang Y. Zhou
, Serguei N. Lvov
, Harry R. Allcock

Research output: Contribution to journal › Review article › peer-review

121 Scopus citations

Abstract

The synthesis of a sulfonimide bearing phenolic compound and its use in the classical macromolecular substitution approach to produce a phosphazene polymer bearing pendent sulfonimide groups were presented. Membranes were cast from 1,4-dioxane and were characterized before and after crosslinking with respect to their proton conductivity, water swelling and thermal properties. A blended membrane of the sulfonimide functionalized polymer with poly (vinylidene fluoride) was also studied.

Original language	English (US)
Pages (from-to)	6490-6493
Number of pages	4
Journal	Macromolecules
Volume	35
Issue number	17
DOIs	https://doi.org/10.1021/ma020330z
State	Published - Aug 13 2002

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma020330z

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title = "Synthesis of polyphosphazenes with sulfonimide side groups",

abstract = "The synthesis of a sulfonimide bearing phenolic compound and its use in the classical macromolecular substitution approach to produce a phosphazene polymer bearing pendent sulfonimide groups were presented. Membranes were cast from 1,4-dioxane and were characterized before and after crosslinking with respect to their proton conductivity, water swelling and thermal properties. A blended membrane of the sulfonimide functionalized polymer with poly (vinylidene fluoride) was also studied.",

author = "Hofmann, \{Michael A.\} and Ambler, \{Catherine M.\} and Maher, \{Andrew E.\} and Elena Chalkova and Zhou, \{Xiangyang Y.\} and Lvov, \{Serguei N.\} and Allcock, \{Harry R.\}",

year = "2002",

month = aug,

day = "13",

doi = "10.1021/ma020330z",

language = "English (US)",

volume = "35",

pages = "6490--6493",

journal = "Macromolecules",

issn = "0024-9297",

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T1 - Synthesis of polyphosphazenes with sulfonimide side groups

AU - Hofmann, Michael A.

AU - Ambler, Catherine M.

AU - Maher, Andrew E.

AU - Chalkova, Elena

AU - Zhou, Xiangyang Y.

AU - Lvov, Serguei N.

AU - Allcock, Harry R.

PY - 2002/8/13

Y1 - 2002/8/13

N2 - The synthesis of a sulfonimide bearing phenolic compound and its use in the classical macromolecular substitution approach to produce a phosphazene polymer bearing pendent sulfonimide groups were presented. Membranes were cast from 1,4-dioxane and were characterized before and after crosslinking with respect to their proton conductivity, water swelling and thermal properties. A blended membrane of the sulfonimide functionalized polymer with poly (vinylidene fluoride) was also studied.

AB - The synthesis of a sulfonimide bearing phenolic compound and its use in the classical macromolecular substitution approach to produce a phosphazene polymer bearing pendent sulfonimide groups were presented. Membranes were cast from 1,4-dioxane and were characterized before and after crosslinking with respect to their proton conductivity, water swelling and thermal properties. A blended membrane of the sulfonimide functionalized polymer with poly (vinylidene fluoride) was also studied.

UR - https://www.scopus.com/pages/publications/0037072355

UR - https://www.scopus.com/pages/publications/0037072355#tab=citedBy

U2 - 10.1021/ma020330z

DO - 10.1021/ma020330z

M3 - Review article

AN - SCOPUS:0037072355

SN - 0024-9297

VL - 35

SP - 6490

EP - 6493

JO - Macromolecules

JF - Macromolecules

IS - 17

ER -

Synthesis of polyphosphazenes with sulfonimide side groups

Abstract

All Science Journal Classification (ASJC) codes

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