Template-Controlled Oligomerization Support Studies. Template Synthesis and Functionalization

Ken S. Feldman; John S. Bobc; Susan M. Ensel; Yoon B. Lee; Paul H. Weinreb

doi:10.1021/jo00289a019

Template-Controlled Oligomerization Support Studies. Template Synthesis and Functionalization

Ken S. Feldman
, John S. Bobc
, Susan M. Ensel
, Yoon B. Lee
, Paul H. Weinreb

Chemistry

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The rigid organic template 8 can be rapidly assembled via double Diels-Alder cycloaddition of methyl 9-anthracenecarboxylate (7) and trams-anti-trans-norbornadiene trimer 5. Subsequent manipulation leads to differentially functionalized templates capable of mediating the oligoselective polymerization of acrylate monomers. Lactonization studies with template diol 10 provide a useful measure of the “effective molecular size” of the template.

Original language	English (US)
Pages (from-to)	474-481
Number of pages	8
Journal	Journal of Organic Chemistry
Volume	55
Issue number	2
DOIs	https://doi.org/10.1021/jo00289a019
State	Published - Jan 1 1990

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1021/jo00289a019

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abstract = "The rigid organic template 8 can be rapidly assembled via double Diels-Alder cycloaddition of methyl 9-anthracenecarboxylate (7) and trams-anti-trans-norbornadiene trimer 5. Subsequent manipulation leads to differentially functionalized templates capable of mediating the oligoselective polymerization of acrylate monomers. Lactonization studies with template diol 10 provide a useful measure of the “effective molecular size” of the template.",

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AU - Feldman, Ken S.

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AU - Lee, Yoon B.

AU - Weinreb, Paul H.

PY - 1990/1/1

Y1 - 1990/1/1

N2 - The rigid organic template 8 can be rapidly assembled via double Diels-Alder cycloaddition of methyl 9-anthracenecarboxylate (7) and trams-anti-trans-norbornadiene trimer 5. Subsequent manipulation leads to differentially functionalized templates capable of mediating the oligoselective polymerization of acrylate monomers. Lactonization studies with template diol 10 provide a useful measure of the “effective molecular size” of the template.

AB - The rigid organic template 8 can be rapidly assembled via double Diels-Alder cycloaddition of methyl 9-anthracenecarboxylate (7) and trams-anti-trans-norbornadiene trimer 5. Subsequent manipulation leads to differentially functionalized templates capable of mediating the oligoselective polymerization of acrylate monomers. Lactonization studies with template diol 10 provide a useful measure of the “effective molecular size” of the template.

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ER -

Template-Controlled Oligomerization Support Studies. Template Synthesis and Functionalization

Abstract

All Science Journal Classification (ASJC) codes

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