[Te2As2]2-: A planar motif with "conflicting" aromaticity

Angel Ugrinov; Ayusman Sen; Arthur C. Reber; Meichun Qian; Shiv N. Khanna

doi:10.1021/ja075513l

[Te₂As₂]^2-: A planar motif with "conflicting" aromaticity

Angel Ugrinov, Ayusman Sen, Arthur C. Reber, Meichun Qian, Shiv N. Khanna

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

[K(18-crown-6)]₂[Te₂As₂] is the first four-membered ring Zintl anion of elements from groups XV and XVI. The anion has an unexpected triplet aromatic ground state.

Original language	English (US)
Pages (from-to)	782-783
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	3
DOIs	https://doi.org/10.1021/ja075513l
State	Published - Jan 23 2008

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja075513l

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abstract = "[K(18-crown-6)]2[Te2As2] is the first four-membered ring Zintl anion of elements from groups XV and XVI. The anion has an unexpected triplet aromatic ground state.",

author = "Angel Ugrinov and Ayusman Sen and Reber, {Arthur C.} and Meichun Qian and Khanna, {Shiv N.}",

year = "2008",

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T1 - [Te2As2]2-

T2 - A planar motif with "conflicting" aromaticity

AU - Ugrinov, Angel

AU - Sen, Ayusman

AU - Reber, Arthur C.

AU - Qian, Meichun

AU - Khanna, Shiv N.

PY - 2008/1/23

Y1 - 2008/1/23

N2 - [K(18-crown-6)]2[Te2As2] is the first four-membered ring Zintl anion of elements from groups XV and XVI. The anion has an unexpected triplet aromatic ground state.

AB - [K(18-crown-6)]2[Te2As2] is the first four-membered ring Zintl anion of elements from groups XV and XVI. The anion has an unexpected triplet aromatic ground state.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 3

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[Te₂As₂]^2-: A planar motif with "conflicting" aromaticity

Abstract

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