The curing of a bisphenol A‐type epoxy resin with 1,8 diamino‐p‐menthane

Thomas Donnellan; David Roylance

doi:10.1002/pen.760221306

The curing of a bisphenol A‐type epoxy resin with 1,8 diamino‐p‐menthane

Thomas Donnellan, David Roylance

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Differential Scanning Calorimetry(DSC), Torsional Braid Analysis (TBA), and Fourier Transform Infrared Spectroscopy (FT‐IR) were used to study the cure characteristics of an epoxy system that utilized a sterically hindered amine curing agent. The apparent activation energy was found to be 13.3 kCal./Mol. by DSC and 12.8 kCal./Mol. by FT‐IR. Resin volatility hindered useful application of conventional TBA techniques. The resin was found to react to a partially cured (52%) state at room temperature and then vitrify. Samples stored for a two‐month period showed no advance in cure state. Subsequent application of heat caused resin devitrification and advance to a more fully cured state. The isothermal curing behavior was studied in a temperature range from 100° to 150°C.

Original language	English (US)
Pages (from-to)	821-825
Number of pages	5
Journal	Polymer Engineering & Science
Volume	22
Issue number	13
DOIs	https://doi.org/10.1002/pen.760221306
State	Published - Sep 1982

All Science Journal Classification (ASJC) codes

General Chemistry
Polymers and Plastics
Materials Chemistry

Access to Document

10.1002/pen.760221306

Cite this

@article{71952f7feda040d78fb8b953b79280b1,

title = "The curing of a bisphenol A‐type epoxy resin with 1,8 diamino‐p‐menthane",

abstract = "Differential Scanning Calorimetry(DSC), Torsional Braid Analysis (TBA), and Fourier Transform Infrared Spectroscopy (FT‐IR) were used to study the cure characteristics of an epoxy system that utilized a sterically hindered amine curing agent. The apparent activation energy was found to be 13.3 kCal./Mol. by DSC and 12.8 kCal./Mol. by FT‐IR. Resin volatility hindered useful application of conventional TBA techniques. The resin was found to react to a partially cured (52\%) state at room temperature and then vitrify. Samples stored for a two‐month period showed no advance in cure state. Subsequent application of heat caused resin devitrification and advance to a more fully cured state. The isothermal curing behavior was studied in a temperature range from 100° to 150°C.",

author = "Thomas Donnellan and David Roylance",

year = "1982",

month = sep,

doi = "10.1002/pen.760221306",

language = "English (US)",

volume = "22",

pages = "821--825",

journal = "Polymer Engineering \& Science",

issn = "0032-3888",

publisher = "John Wiley and Sons Inc.",

number = "13",

}

TY - JOUR

T1 - The curing of a bisphenol A‐type epoxy resin with 1,8 diamino‐p‐menthane

AU - Donnellan, Thomas

AU - Roylance, David

PY - 1982/9

Y1 - 1982/9

N2 - Differential Scanning Calorimetry(DSC), Torsional Braid Analysis (TBA), and Fourier Transform Infrared Spectroscopy (FT‐IR) were used to study the cure characteristics of an epoxy system that utilized a sterically hindered amine curing agent. The apparent activation energy was found to be 13.3 kCal./Mol. by DSC and 12.8 kCal./Mol. by FT‐IR. Resin volatility hindered useful application of conventional TBA techniques. The resin was found to react to a partially cured (52%) state at room temperature and then vitrify. Samples stored for a two‐month period showed no advance in cure state. Subsequent application of heat caused resin devitrification and advance to a more fully cured state. The isothermal curing behavior was studied in a temperature range from 100° to 150°C.

AB - Differential Scanning Calorimetry(DSC), Torsional Braid Analysis (TBA), and Fourier Transform Infrared Spectroscopy (FT‐IR) were used to study the cure characteristics of an epoxy system that utilized a sterically hindered amine curing agent. The apparent activation energy was found to be 13.3 kCal./Mol. by DSC and 12.8 kCal./Mol. by FT‐IR. Resin volatility hindered useful application of conventional TBA techniques. The resin was found to react to a partially cured (52%) state at room temperature and then vitrify. Samples stored for a two‐month period showed no advance in cure state. Subsequent application of heat caused resin devitrification and advance to a more fully cured state. The isothermal curing behavior was studied in a temperature range from 100° to 150°C.

UR - https://www.scopus.com/pages/publications/0020182952

UR - https://www.scopus.com/inward/citedby.url?scp=0020182952&partnerID=8YFLogxK

U2 - 10.1002/pen.760221306

DO - 10.1002/pen.760221306

M3 - Article

AN - SCOPUS:0020182952

SN - 0032-3888

VL - 22

SP - 821

EP - 825

JO - Polymer Engineering & Science

JF - Polymer Engineering & Science

IS - 13

ER -

The curing of a bisphenol A‐type epoxy resin with 1,8 diamino‐p‐menthane

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this