The diluted stoichiometric oxidation of iso-octane in the intermediate temperature regime at elevated pressures

J. S. Chen; T. A. Litzinger; H. J. Curran

doi:10.1080/00102200108935838

The diluted stoichiometric oxidation of iso-octane in the intermediate temperature regime at elevated pressures

J. S. Chen, T. A. Litzinger, H. J. Curran

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Experimental and modeling results for dilute stoichiometric oxidation of iso-octane in the intermediate temperature regime are presented for pressures of 6 and 9 atmospheres. While the overall comparison between the experiments and modeling is acceptable, important differences exist in the predictions of the mole fractions of acetone and methacrolein, which are products of isobutene oxidation. The results from this study are compared to earlier work on the oxidation iso-octane under very lean conditions to illustrate the significance of chemical pathways in which molecular oxygen is a key reactant.

Original language	English (US)
Pages (from-to)	71-80
Number of pages	10
Journal	Combustion science and technology
Volume	172
Issue number	1
DOIs	https://doi.org/10.1080/00102200108935838
State	Published - 2001

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology
General Physics and Astronomy

Access to Document

10.1080/00102200108935838

Cite this

@article{10b19e13e26d4ef083b234d73ab612d0,

title = "The diluted stoichiometric oxidation of iso-octane in the intermediate temperature regime at elevated pressures",

abstract = "Experimental and modeling results for dilute stoichiometric oxidation of iso-octane in the intermediate temperature regime are presented for pressures of 6 and 9 atmospheres. While the overall comparison between the experiments and modeling is acceptable, important differences exist in the predictions of the mole fractions of acetone and methacrolein, which are products of isobutene oxidation. The results from this study are compared to earlier work on the oxidation iso-octane under very lean conditions to illustrate the significance of chemical pathways in which molecular oxygen is a key reactant.",

author = "Chen, {J. S.} and Litzinger, {T. A.} and Curran, {H. J.}",

note = "Funding Information: Received II September 2001; accepted 10 October 2001. The authors gratefully acknowledge partial support of this work by Texaco, This work was performed under the auspices of the U.S. Department of Energy by the Lawrence Livermore National Laboratory under contract no. W-7405-ENG-48. t Current address of J.-S. Chen: Cummins Inc., MC 50183, 1900 McKinley Ave., Columbus, IN 47201. USA. t Current address of H. J. Curran: Chemistry Department, Galway-Mayo Institute of Technology, Galway, Ireland. • Address correspondence to taI2@psu,edu",

year = "2001",

doi = "10.1080/00102200108935838",

language = "English (US)",

volume = "172",

pages = "71--80",

journal = "Combustion science and technology",

issn = "0010-2202",

publisher = "Taylor and Francis Ltd.",

number = "1",

}

TY - JOUR

T1 - The diluted stoichiometric oxidation of iso-octane in the intermediate temperature regime at elevated pressures

AU - Chen, J. S.

AU - Litzinger, T. A.

AU - Curran, H. J.

N1 - Funding Information: Received II September 2001; accepted 10 October 2001. The authors gratefully acknowledge partial support of this work by Texaco, This work was performed under the auspices of the U.S. Department of Energy by the Lawrence Livermore National Laboratory under contract no. W-7405-ENG-48. t Current address of J.-S. Chen: Cummins Inc., MC 50183, 1900 McKinley Ave., Columbus, IN 47201. USA. t Current address of H. J. Curran: Chemistry Department, Galway-Mayo Institute of Technology, Galway, Ireland. • Address correspondence to taI2@psu,edu

PY - 2001

Y1 - 2001

N2 - Experimental and modeling results for dilute stoichiometric oxidation of iso-octane in the intermediate temperature regime are presented for pressures of 6 and 9 atmospheres. While the overall comparison between the experiments and modeling is acceptable, important differences exist in the predictions of the mole fractions of acetone and methacrolein, which are products of isobutene oxidation. The results from this study are compared to earlier work on the oxidation iso-octane under very lean conditions to illustrate the significance of chemical pathways in which molecular oxygen is a key reactant.

AB - Experimental and modeling results for dilute stoichiometric oxidation of iso-octane in the intermediate temperature regime are presented for pressures of 6 and 9 atmospheres. While the overall comparison between the experiments and modeling is acceptable, important differences exist in the predictions of the mole fractions of acetone and methacrolein, which are products of isobutene oxidation. The results from this study are compared to earlier work on the oxidation iso-octane under very lean conditions to illustrate the significance of chemical pathways in which molecular oxygen is a key reactant.

UR - http://www.scopus.com/inward/record.url?scp=0346307501&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0346307501&partnerID=8YFLogxK

U2 - 10.1080/00102200108935838

DO - 10.1080/00102200108935838

M3 - Article

AN - SCOPUS:0346307501

SN - 0010-2202

VL - 172

SP - 71

EP - 80

JO - Combustion science and technology

JF - Combustion science and technology

IS - 1

ER -

The diluted stoichiometric oxidation of iso-octane in the intermediate temperature regime at elevated pressures

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this