The novel acid catalysts - Framework zirconium phosphates: The bulk and surface structure

  • S. N. Pavlova
  • , V. A. Sadykov
  • , G. V. Zabolotnaya
  • , D. I. Kochubey
  • , R. I. Maximovskaya
  • , V. I. Zaikovskii
  • , V. V. Kriventsov
  • , S. V. Tsybulya
  • , E. B. Burgina
  • , A. M. Volodin
  • , M. V. Chaikina
  • , N. N. Kuznetsova
  • , V. V. Lunin
  • , D. Agrawal
  • , R. Roy

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Structural features and surface properties of framework zirconium phosphates synthesized via mechanochemical activation (MA) and sol-gel (SG) route were studied using XRD, TEM, 31P MAS NMR, IR and ESR spectroscopy and compared with their catalytic performance in the reaction of hexane isomerization. A high initial isomerization activity of crystalline zirconium phosphates prepared via MA can be determined by a larger share of the strong Lewis centers probed by TEMPON test molecule. (C) 2000 Elsevier Science B.V.

Original languageEnglish (US)
Pages (from-to)319-323
Number of pages5
JournalJournal of Molecular Catalysis A: Chemical
Volume158
Issue number1
DOIs
StatePublished - Sep 8 2000

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Process Chemistry and Technology
  • Physical and Theoretical Chemistry

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