The synthesis and characterizations of monodisperse cross-linked polymer microspheres with carboxyl on the surface

Xin Chen; Zhanchen Cui; Zhimin Chen; Kai Zhang; Guang Lu; Gang Zhang; Bai Yang

doi:10.1016/S0032-3861(02)00262-8

The synthesis and characterizations of monodisperse cross-linked polymer microspheres with carboxyl on the surface

Xin Chen, Zhanchen Cui, Zhimin Chen, Kai Zhang, Guang Lu, Gang Zhang, Bai Yang

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

Monodisperse cross-linked polymer microspheres with carboxyl groups on their surface were prepared by means of emulsifier-free emulsion copolymerization. The characterizations by X-ray photoelectron spectroscopy and conductometric titration indicate that most carboxyl groups are located on the surface of microspheres. Their swelling degree or cross-linking degree has been investigated by an in situ swelling method. Moreover, these microspheres can be easily and quickly self-organized into two- or three-dimensional ordered multilayer films or latex crystals.

Original language	English (US)
Pages (from-to)	4147-4152
Number of pages	6
Journal	Polymer
Volume	43
Issue number	15
DOIs	https://doi.org/10.1016/S0032-3861(02)00262-8
State	Published - May 23 2002

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1016/S0032-3861(02)00262-8

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title = "The synthesis and characterizations of monodisperse cross-linked polymer microspheres with carboxyl on the surface",

abstract = "Monodisperse cross-linked polymer microspheres with carboxyl groups on their surface were prepared by means of emulsifier-free emulsion copolymerization. The characterizations by X-ray photoelectron spectroscopy and conductometric titration indicate that most carboxyl groups are located on the surface of microspheres. Their swelling degree or cross-linking degree has been investigated by an in situ swelling method. Moreover, these microspheres can be easily and quickly self-organized into two- or three-dimensional ordered multilayer films or latex crystals.",

author = "Xin Chen and Zhanchen Cui and Zhimin Chen and Kai Zhang and Guang Lu and Gang Zhang and Bai Yang",

note = "Funding Information: This work was supported by The Special Funds For Major State Basic Research Projects (project No. G1999064803) and The National Natural Science Foundation of China (No. 200340062 and No. 29925412).",

year = "2002",

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TY - JOUR

T1 - The synthesis and characterizations of monodisperse cross-linked polymer microspheres with carboxyl on the surface

AU - Chen, Xin

AU - Cui, Zhanchen

AU - Chen, Zhimin

AU - Zhang, Kai

AU - Lu, Guang

AU - Zhang, Gang

AU - Yang, Bai

N1 - Funding Information: This work was supported by The Special Funds For Major State Basic Research Projects (project No. G1999064803) and The National Natural Science Foundation of China (No. 200340062 and No. 29925412).

PY - 2002/5/23

Y1 - 2002/5/23

N2 - Monodisperse cross-linked polymer microspheres with carboxyl groups on their surface were prepared by means of emulsifier-free emulsion copolymerization. The characterizations by X-ray photoelectron spectroscopy and conductometric titration indicate that most carboxyl groups are located on the surface of microspheres. Their swelling degree or cross-linking degree has been investigated by an in situ swelling method. Moreover, these microspheres can be easily and quickly self-organized into two- or three-dimensional ordered multilayer films or latex crystals.

AB - Monodisperse cross-linked polymer microspheres with carboxyl groups on their surface were prepared by means of emulsifier-free emulsion copolymerization. The characterizations by X-ray photoelectron spectroscopy and conductometric titration indicate that most carboxyl groups are located on the surface of microspheres. Their swelling degree or cross-linking degree has been investigated by an in situ swelling method. Moreover, these microspheres can be easily and quickly self-organized into two- or three-dimensional ordered multilayer films or latex crystals.

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The synthesis and characterizations of monodisperse cross-linked polymer microspheres with carboxyl on the surface

Abstract

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