TY - JOUR
T1 - The temperature dependent luminescent decay kinetics of an emissive copper complex in the single crystalline phase using time-gated luminescence microscopy
AU - Linderman, Crysania M.
AU - Coppin, Jarrett A.
AU - O'Brien, Corey
AU - Cox, Jordan M.
AU - Patel, Dinesh G.
AU - Benedict, Jason B.
N1 - Publisher Copyright:
© 2015 Elsevier B.V. All rights reserved.
PY - 2016/5
Y1 - 2016/5
N2 - The temperature dependence of the luminescent lifetime of a single crystal of Cu(I) phenanthroline, [Cu(dmp)(PPh3)2]BF4 (dmp=2,9-dimethyl-1,10-phenanthroline and PPh3=triphenylphosphine), was measured using a fluorescence lifetime imaging microscope utilizing time-gated CCD detection. At all temperatures between 100 K and 292 K, the single crystals exhibited biexponential luminescent decay as well as non-linear Arrhenius luminescent decay kinetics. Variable temperature single-crystal XRD measurements revealed that the observed behavior is likely not the result of a crystallographic phase transition.
AB - The temperature dependence of the luminescent lifetime of a single crystal of Cu(I) phenanthroline, [Cu(dmp)(PPh3)2]BF4 (dmp=2,9-dimethyl-1,10-phenanthroline and PPh3=triphenylphosphine), was measured using a fluorescence lifetime imaging microscope utilizing time-gated CCD detection. At all temperatures between 100 K and 292 K, the single crystals exhibited biexponential luminescent decay as well as non-linear Arrhenius luminescent decay kinetics. Variable temperature single-crystal XRD measurements revealed that the observed behavior is likely not the result of a crystallographic phase transition.
UR - http://www.scopus.com/inward/record.url?scp=84954443466&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84954443466&partnerID=8YFLogxK
U2 - 10.1016/j.jlumin.2015.12.027
DO - 10.1016/j.jlumin.2015.12.027
M3 - Article
AN - SCOPUS:84954443466
SN - 0022-2313
VL - 173
SP - 30
EP - 33
JO - Journal of Luminescence
JF - Journal of Luminescence
ER -