The use of catalytic hydrogenation to intercept carbohydrates in a dilute acid hydrolysis of biomass to effect a clean separation from lignin

J. Michael Robinson; Caroline E. Burgess; Melissa A. Bently; Chris D. Brasher; Bruce O. Horne; Danny M. Lillard; José M. Macias; Hari D. Mandal; Samuel C. Mills; Kevin D. O'Hara; Justin T. Pon; Annette F. Raigoza; Ernesto H. Sanchez; José S. Villarreal

doi:10.1016/j.biombioe.2003.09.005

The use of catalytic hydrogenation to intercept carbohydrates in a dilute acid hydrolysis of biomass to effect a clean separation from lignin

J. Michael Robinson, Caroline E. Burgess, Melissa A. Bently, Chris D. Brasher, Bruce O. Horne, Danny M. Lillard, José M. Macias, Hari D. Mandal, Samuel C. Mills, Kevin D. O'Hara, Justin T. Pon, Annette F. Raigoza, Ernesto H. Sanchez, José S. Villarreal

Agricultural & Biological Engineering

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Biomass carbohydrates are fractionated very cleanly (>99%) from unreacted insoluble lignin by a dilute acid hydrolysis (0.35-1.5% H ₃PO₄), wherein the incipient aldoses are intercepted by catalytic hydrogenation (Ru/C) to produce a solution of C₅-C ₆ polyols (xylitol, sorbitol) and anhydro polyols (sorbitan) in which no phenols could be detected (<100 ppm). A screen removes granular catalyst and lignin is simply filtered from the product slurry. This "intercepted dilute acid hydrolysis" (IDAH) of biomass to polyols affords high conversion for a variety of biomass types within 3-6 h at ∼185°C. Minimum polyols cost (not including catalyst cost) is calculated to range from $0.055-$0.070 kg^-1. Polyols, rather than aldoses, are required for subsequent chemical conversion into hydrocarbon fuels.

Original language	English (US)
Pages (from-to)	473-483
Number of pages	11
Journal	Biomass and Bioenergy
Volume	26
Issue number	5
DOIs	https://doi.org/10.1016/j.biombioe.2003.09.005
State	Published - May 2004

All Science Journal Classification (ASJC) codes

Forestry
Renewable Energy, Sustainability and the Environment
Agronomy and Crop Science
Waste Management and Disposal

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.biombioe.2003.09.005

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Robinson, J. M., Burgess, C. E., Bently, M. A., Brasher, C. D., Horne, B. O., Lillard, D. M., Macias, J. M., Mandal, H. D., Mills, S. C., O'Hara, K. D., Pon, J. T., Raigoza, A. F., Sanchez, E. H., & Villarreal, J. S. (2004). The use of catalytic hydrogenation to intercept carbohydrates in a dilute acid hydrolysis of biomass to effect a clean separation from lignin. Biomass and Bioenergy, 26(5), 473-483. https://doi.org/10.1016/j.biombioe.2003.09.005

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title = "The use of catalytic hydrogenation to intercept carbohydrates in a dilute acid hydrolysis of biomass to effect a clean separation from lignin",

abstract = "Biomass carbohydrates are fractionated very cleanly (>99%) from unreacted insoluble lignin by a dilute acid hydrolysis (0.35-1.5% H 3PO4), wherein the incipient aldoses are intercepted by catalytic hydrogenation (Ru/C) to produce a solution of C5-C 6 polyols (xylitol, sorbitol) and anhydro polyols (sorbitan) in which no phenols could be detected (<100 ppm). A screen removes granular catalyst and lignin is simply filtered from the product slurry. This {"}intercepted dilute acid hydrolysis{"} (IDAH) of biomass to polyols affords high conversion for a variety of biomass types within 3-6 h at ∼185°C. Minimum polyols cost (not including catalyst cost) is calculated to range from $0.055-$0.070 kg-1. Polyols, rather than aldoses, are required for subsequent chemical conversion into hydrocarbon fuels.",

author = "Robinson, {J. Michael} and Burgess, {Caroline E.} and Bently, {Melissa A.} and Brasher, {Chris D.} and Horne, {Bruce O.} and Lillard, {Danny M.} and Macias, {Jos{\'e} M.} and Mandal, {Hari D.} and Mills, {Samuel C.} and O'Hara, {Kevin D.} and Pon, {Justin T.} and Raigoza, {Annette F.} and Sanchez, {Ernesto H.} and Villarreal, {Jos{\'e} S.}",

note = "Funding Information: The Robert A. Welch Foundation Chemistry Department Grant, a US Department of Energy, Basic Energy Sciences, Advanced Research Projects grant and the Texas Higher Education Coordinating Board, Advanced Technology Program have supported this research. ",

year = "2004",

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doi = "10.1016/j.biombioe.2003.09.005",

language = "English (US)",

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pages = "473--483",

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Robinson, JM, Burgess, CE, Bently, MA, Brasher, CD, Horne, BO, Lillard, DM, Macias, JM, Mandal, HD, Mills, SC, O'Hara, KD, Pon, JT, Raigoza, AF, Sanchez, EH & Villarreal, JS 2004, 'The use of catalytic hydrogenation to intercept carbohydrates in a dilute acid hydrolysis of biomass to effect a clean separation from lignin', Biomass and Bioenergy, vol. 26, no. 5, pp. 473-483. https://doi.org/10.1016/j.biombioe.2003.09.005

TY - JOUR

T1 - The use of catalytic hydrogenation to intercept carbohydrates in a dilute acid hydrolysis of biomass to effect a clean separation from lignin

AU - Robinson, J. Michael

AU - Burgess, Caroline E.

AU - Bently, Melissa A.

AU - Brasher, Chris D.

AU - Horne, Bruce O.

AU - Lillard, Danny M.

AU - Macias, José M.

AU - Mandal, Hari D.

AU - Mills, Samuel C.

AU - O'Hara, Kevin D.

AU - Pon, Justin T.

AU - Raigoza, Annette F.

AU - Sanchez, Ernesto H.

AU - Villarreal, José S.

N1 - Funding Information: The Robert A. Welch Foundation Chemistry Department Grant, a US Department of Energy, Basic Energy Sciences, Advanced Research Projects grant and the Texas Higher Education Coordinating Board, Advanced Technology Program have supported this research.

PY - 2004/5

Y1 - 2004/5

N2 - Biomass carbohydrates are fractionated very cleanly (>99%) from unreacted insoluble lignin by a dilute acid hydrolysis (0.35-1.5% H 3PO4), wherein the incipient aldoses are intercepted by catalytic hydrogenation (Ru/C) to produce a solution of C5-C 6 polyols (xylitol, sorbitol) and anhydro polyols (sorbitan) in which no phenols could be detected (<100 ppm). A screen removes granular catalyst and lignin is simply filtered from the product slurry. This "intercepted dilute acid hydrolysis" (IDAH) of biomass to polyols affords high conversion for a variety of biomass types within 3-6 h at ∼185°C. Minimum polyols cost (not including catalyst cost) is calculated to range from $0.055-$0.070 kg-1. Polyols, rather than aldoses, are required for subsequent chemical conversion into hydrocarbon fuels.

AB - Biomass carbohydrates are fractionated very cleanly (>99%) from unreacted insoluble lignin by a dilute acid hydrolysis (0.35-1.5% H 3PO4), wherein the incipient aldoses are intercepted by catalytic hydrogenation (Ru/C) to produce a solution of C5-C 6 polyols (xylitol, sorbitol) and anhydro polyols (sorbitan) in which no phenols could be detected (<100 ppm). A screen removes granular catalyst and lignin is simply filtered from the product slurry. This "intercepted dilute acid hydrolysis" (IDAH) of biomass to polyols affords high conversion for a variety of biomass types within 3-6 h at ∼185°C. Minimum polyols cost (not including catalyst cost) is calculated to range from $0.055-$0.070 kg-1. Polyols, rather than aldoses, are required for subsequent chemical conversion into hydrocarbon fuels.

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The use of catalytic hydrogenation to intercept carbohydrates in a dilute acid hydrolysis of biomass to effect a clean separation from lignin

Abstract

All Science Journal Classification (ASJC) codes

UN SDGs

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