Thermodynamic investigation of the galvanizing systems, I: Refinement of the thermodynamic description for the Fe-Zn system

Wei Xiong, Yi Kong, Yong Du, Zi Kui Liu, Malin Selleby, Wei Hua Sun

Research output: Contribution to journalArticlepeer-review

47 Scopus citations

Abstract

The thermodynamic description for the Fe-Zn system was updated using CALPHAD approach. A set of self-consistent thermodynamic model parameters for this system was obtained by considering the available experimental data. Compared with the previous thermodynamic modeling, the present assessment with fewer parameters shows not only a better agreement with the experiments but also sounder physical meaning. The present CALPHAD modeling coupled with the ab initio calculations were used to predict the enthalpies of formation of the solid phases in the Fe-Zn system.

Original languageEnglish (US)
Pages (from-to)433-440
Number of pages8
JournalCalphad: Computer Coupling of Phase Diagrams and Thermochemistry
Volume33
Issue number2
DOIs
StatePublished - Jun 2009

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • General Chemical Engineering
  • Computer Science Applications

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