TY - JOUR
T1 - Thermodynamic modeling of the indium-palladium system
AU - Jiang, Chao
AU - Liu, Zi Kui
N1 - Funding Information:
The authors gratefully acknowledge the financial support from a Wilson Research Initiation Grant, College of Earth
Funding Information:
and Mineral Science, Pennsylvania State University, and the National Science Foundation, through CAREER Award No. 9983532. All calculations are performed using the Thermo-Calc program licensed from The Foundation for Computational Thermodynamics (Stockholm, Sweden).
PY - 2002/12
Y1 - 2002/12
N2 - The thermochemical and phase-equilibrium data of the In-Pd binary system were critically reviewed. A self-consistent thermodynamic description of the system was obtained using the CALPHAD approach. Eight intermetallic compounds were considered in the system. The InPd(B2) compound was described by a two-sublattice model. The compounds In7Pd3, In3Pd2, In3Pd5, αInPd2, and αInPd3, with negligible homogeneity ranges, were modeled as stoichiometric compounds. βInPd2 and βInPd3 were treated as stoichiometric compounds due to a lack of experimental information. Model calculations agreed satisfactorily with most existing experimental data. The thermodynamic factor for the InPd(B2) compound was also predicted based on the present thermodynamic description.
AB - The thermochemical and phase-equilibrium data of the In-Pd binary system were critically reviewed. A self-consistent thermodynamic description of the system was obtained using the CALPHAD approach. Eight intermetallic compounds were considered in the system. The InPd(B2) compound was described by a two-sublattice model. The compounds In7Pd3, In3Pd2, In3Pd5, αInPd2, and αInPd3, with negligible homogeneity ranges, were modeled as stoichiometric compounds. βInPd2 and βInPd3 were treated as stoichiometric compounds due to a lack of experimental information. Model calculations agreed satisfactorily with most existing experimental data. The thermodynamic factor for the InPd(B2) compound was also predicted based on the present thermodynamic description.
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U2 - 10.1007/s11661-002-0235-x
DO - 10.1007/s11661-002-0235-x
M3 - Article
AN - SCOPUS:0036992213
SN - 1073-5623
VL - 33
SP - 3597
EP - 3603
JO - Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
JF - Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
IS - 12
ER -