Thermodynamic modeling of the YO1.5-ZrO2 system

Nathan S. Jacobson, Zi Kui Liu, Larry Kaufman, Fan Zhang

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

The YO1.5-ZrO2 system consists of five solid solutions, one liquid solution, and one intermediate compound. A thermodynamic description of this system is developed, which allows calculation of the phase diagram and thermodynamic properties. Two different solution models are used - a neutral species model with YO1.5 and ZrO2 as the components and a charged species model with Y3+, Zr4+, O2-, and vacancies as components. For each model, regular and subregular solution parameters are derived from selected phase equilibrium and thermodynamic data. The neutral species and charged species modeling results are compared.

Original languageEnglish (US)
Pages (from-to)1559-1566
Number of pages8
JournalJournal of the American Ceramic Society
Volume87
Issue number8
DOIs
StatePublished - Aug 2004

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

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