Third-order nonlinear optical properties of [(C2H 5)4N][Co(dmit)2] using Z-scan technique

Xi Zhang; Quan Ren; Wen Feng Guo; Xiang Bing Sun; Xin Qiang Wang; Hong Liang Yang; Fu Jun Zhang; Yi Gao; Dong Xu

doi:10.1142/S0217984908014651

Third-order nonlinear optical properties of [(C₂H ₅)₄N][Co(dmit)₂] using Z-scan technique

Xi Zhang
, Quan Ren
, Wen Feng Guo
, Xiang Bing Sun
, Xin Qiang Wang
, Hong Liang Yang
, Fu Jun Zhang
, Yi Gao
, Dong Xu

Engineering Division (Great Valley)

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A novel dmit^2- complex: [(C₂H₅) ₄N][Co(dmit)₂], abbreviated as EtCo, was synthesized and its third-order optical nonlinearities were characterized by Z-scan technique at the wavelength of 1064 nm with laser duration of 40 ps. Z-scan curves revealed a negative nonlinear refraction at 1064 nm and a positive absorption was observed. The nonlinear refraction coefficient n₂, the nonlinear absorption coefficient β and the molecular second hyperpolarizability γ have been determined to be as large as 9.51 × 10^-19 m²/W, 2.19 × 10^-12 m/W and 5.41 × 10 ^-31 esu respectively, suggesting that this material has potential applications in optical limiting.

Original language	English (US)
Pages (from-to)	191-198
Number of pages	8
Journal	Modern Physics Letters B
Volume	22
Issue number	3
DOIs	https://doi.org/10.1142/S0217984908014651
State	Published - Jan 30 2008

All Science Journal Classification (ASJC) codes

Statistical and Nonlinear Physics
Condensed Matter Physics

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@article{c92fa99760184e9ab0cf57c3df7db460,

title = "Third-order nonlinear optical properties of [(C2H 5)4N][Co(dmit)2] using Z-scan technique",

abstract = "A novel dmit2- complex: [(C2H5) 4N][Co(dmit)2], abbreviated as EtCo, was synthesized and its third-order optical nonlinearities were characterized by Z-scan technique at the wavelength of 1064 nm with laser duration of 40 ps. Z-scan curves revealed a negative nonlinear refraction at 1064 nm and a positive absorption was observed. The nonlinear refraction coefficient n2, the nonlinear absorption coefficient β and the molecular second hyperpolarizability γ have been determined to be as large as 9.51 × 10-19 m2/W, 2.19 × 10-12 m/W and 5.41 × 10 -31 esu respectively, suggesting that this material has potential applications in optical limiting.",

author = "Xi Zhang and Quan Ren and Guo, \{Wen Feng\} and Sun, \{Xiang Bing\} and Wang, \{Xin Qiang\} and Yang, \{Hong Liang\} and Zhang, \{Fu Jun\} and Yi Gao and Dong Xu",

note = "Funding Information: This research work is supported by Grant Nos. 60778037, 60608010, 60476020 and 50772059 of the National Natural Science Foundation of China (NNSFC) and the Foundation for the Author of National Excellent Doctoral Dissertation of P. R. China (No. 200539).",

year = "2008",

month = jan,

day = "30",

doi = "10.1142/S0217984908014651",

language = "English (US)",

volume = "22",

pages = "191--198",

journal = "Modern Physics Letters B",

issn = "0217-9849",

publisher = "World Scientific",

number = "3",

}

TY - JOUR

T1 - Third-order nonlinear optical properties of [(C2H 5)4N][Co(dmit)2] using Z-scan technique

AU - Zhang, Xi

AU - Ren, Quan

AU - Guo, Wen Feng

AU - Sun, Xiang Bing

AU - Wang, Xin Qiang

AU - Yang, Hong Liang

AU - Zhang, Fu Jun

AU - Gao, Yi

AU - Xu, Dong

N1 - Funding Information: This research work is supported by Grant Nos. 60778037, 60608010, 60476020 and 50772059 of the National Natural Science Foundation of China (NNSFC) and the Foundation for the Author of National Excellent Doctoral Dissertation of P. R. China (No. 200539).

PY - 2008/1/30

Y1 - 2008/1/30

N2 - A novel dmit2- complex: [(C2H5) 4N][Co(dmit)2], abbreviated as EtCo, was synthesized and its third-order optical nonlinearities were characterized by Z-scan technique at the wavelength of 1064 nm with laser duration of 40 ps. Z-scan curves revealed a negative nonlinear refraction at 1064 nm and a positive absorption was observed. The nonlinear refraction coefficient n2, the nonlinear absorption coefficient β and the molecular second hyperpolarizability γ have been determined to be as large as 9.51 × 10-19 m2/W, 2.19 × 10-12 m/W and 5.41 × 10 -31 esu respectively, suggesting that this material has potential applications in optical limiting.

AB - A novel dmit2- complex: [(C2H5) 4N][Co(dmit)2], abbreviated as EtCo, was synthesized and its third-order optical nonlinearities were characterized by Z-scan technique at the wavelength of 1064 nm with laser duration of 40 ps. Z-scan curves revealed a negative nonlinear refraction at 1064 nm and a positive absorption was observed. The nonlinear refraction coefficient n2, the nonlinear absorption coefficient β and the molecular second hyperpolarizability γ have been determined to be as large as 9.51 × 10-19 m2/W, 2.19 × 10-12 m/W and 5.41 × 10 -31 esu respectively, suggesting that this material has potential applications in optical limiting.

UR - https://www.scopus.com/pages/publications/43949127069

UR - https://www.scopus.com/pages/publications/43949127069#tab=citedBy

U2 - 10.1142/S0217984908014651

DO - 10.1142/S0217984908014651

M3 - Article

AN - SCOPUS:43949127069

SN - 0217-9849

VL - 22

SP - 191

EP - 198

JO - Modern Physics Letters B

JF - Modern Physics Letters B

IS - 3

ER -

Third-order nonlinear optical properties of [(C₂H ₅)₄N][Co(dmit)₂] using Z-scan technique

Abstract

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