Time-resolved Raman spectroscopy of optical phonons in graphite: Phonon anharmonic coupling and anomalous stiffening

  • Hugen Yan
  • , Daohua Song
  • , Kin Fai Mak
  • , Ioannis Chatzakis
  • , Janina Maultzsch
  • , Tony F. Heinz

Research output: Contribution to journalArticlepeer-review

137 Scopus citations

Abstract

Time-resolved Raman spectroscopy has been applied to probe the anharmonic coupling and electron-phonon interaction of optical phonons in graphite. From the decay of the transient anti-Stokes scattering of the G -mode following ultrafast excitation, we measured a lifetime of 2.2±0.1 ps for zone-center optical phonons. We also observed a transient stiffening of G -mode phonons, an effect attributed to the reduction of the electron-phonon coupling for high electronic temperatures.

Original languageEnglish (US)
Article number121403
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume80
Issue number12
DOIs
StatePublished - Sep 17 2009

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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