Abstract
(Chemical Equation Presented) What the Heck: The heptacyclic fungal alkaloid communesin F was the target of a total synthesis featuring a rare example of an intramolecular Heck cyclization of a tetrasubstituted alkene, a reductive cyclization of an N-Boc aniline, a stereoselective C allylation of a lactam, and an azide reduction/N-Boc-d-lactam ring opening sequence (see scheme, BOM=benzyloxymethyl).
Original language | English (US) |
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Pages (from-to) | 2000-2003 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 49 |
Issue number | 11 |
DOIs | |
State | Published - Mar 8 2010 |
All Science Journal Classification (ASJC) codes
- Catalysis
- General Chemistry