TY - JOUR
T1 - Tracing low-temperature aqueous metal migration in mineralized watersheds with Cu isotope fractionation
AU - Mathur, R.
AU - Munk, L. A.
AU - Townley, B.
AU - Gou, K. Y.
AU - Gómez Miguélez, N.
AU - Titley, S.
AU - Chen, G. G.
AU - Song, S.
AU - Reich, M.
AU - Tornos, F.
AU - Ruiz, J.
N1 - Publisher Copyright:
© 2014 Elsevier Ltd.
PY - 2014/12/1
Y1 - 2014/12/1
N2 - Copper isotope signatures in waters emanating from mineralized watersheds provide evidence for the source aqueous copper in solution. Low-temperature aqueous oxidation of Cu sulfide minerals produces significant copper isotopic fractionation between solutions and residues. Abiotic experimental data of fractionation (defined as δliquid-solid ‰=δ65Culiquid-δ65Cusolid) are on the order of 1-3‰ and are unique for copper rich-sulfide minerals. Data presented here from ores and waters within defined boundaries of porphyry copper, massive sulfide, skarn, and epithermal ore deposits mimic abiotic experiments. Thus, the oxidation of sulfide minerals appears to cause the signatures in the waters although significant biological, temperature, and pH variations exist in the fluids. Regardless of the deposit type, water type, concentration of Cu in solution, or location, the data provide a means to trace sources of metals in solutions. This relationship allows for tracking sources and degree of metal migration in low temperature aqueous systems and has direct application to exploration geology and environmental geochemistry.
AB - Copper isotope signatures in waters emanating from mineralized watersheds provide evidence for the source aqueous copper in solution. Low-temperature aqueous oxidation of Cu sulfide minerals produces significant copper isotopic fractionation between solutions and residues. Abiotic experimental data of fractionation (defined as δliquid-solid ‰=δ65Culiquid-δ65Cusolid) are on the order of 1-3‰ and are unique for copper rich-sulfide minerals. Data presented here from ores and waters within defined boundaries of porphyry copper, massive sulfide, skarn, and epithermal ore deposits mimic abiotic experiments. Thus, the oxidation of sulfide minerals appears to cause the signatures in the waters although significant biological, temperature, and pH variations exist in the fluids. Regardless of the deposit type, water type, concentration of Cu in solution, or location, the data provide a means to trace sources of metals in solutions. This relationship allows for tracking sources and degree of metal migration in low temperature aqueous systems and has direct application to exploration geology and environmental geochemistry.
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U2 - 10.1016/j.apgeochem.2014.09.019
DO - 10.1016/j.apgeochem.2014.09.019
M3 - Article
AN - SCOPUS:84908574576
SN - 0883-2927
VL - 51
SP - 109
EP - 115
JO - Applied Geochemistry
JF - Applied Geochemistry
ER -