trans-diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) tetrafluoroborate

Shaun O. Sommerer; Timothy L. Friebe; Alan J. Jircitano; Cora E. Macbeth; Khalil A. Abboud

doi:10.1107/S0108270197014728

trans-diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) tetrafluoroborate

Shaun O. Sommerer, Timothy L. Friebe, Alan J. Jircitano, Cora E. Macbeth, Khalil A. Abboud

School of Science (Behrend)

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The title complex, [Cu(C₁₀H₇NOS)₂(H₂O) ₂](BF₄)₂, contains tetragonally elongated octahedral diaquabis(2-thienyl 2-pyridyl ketone)copper(II) cations counterbalanced with BF₄^- anions. The Cu atom resides on an inversion center and is bonded to the ligand through the pyridine N and the carbonyl O atoms [1.986(2) Å], with a bite angle of 81.39(10)°. The thiophene is not involved in coordination. The coordinated water molecules are hydrogen bridged to adjacent BF₄^- anions, linking the cation and anion in an extended chain.

Original language	English (US)
Pages (from-to)	178-179
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	2
DOIs	https://doi.org/10.1107/S0108270197014728
State	Published - Feb 15 1998

All Science Journal Classification (ASJC) codes

General Biochemistry, Genetics and Molecular Biology

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@article{19ecaf6c30d64fc59c647a57dd026814,

title = "trans-diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) tetrafluoroborate",

abstract = "The title complex, [Cu(C10H7NOS)2(H2O) 2](BF4)2, contains tetragonally elongated octahedral diaquabis(2-thienyl 2-pyridyl ketone)copper(II) cations counterbalanced with BF4- anions. The Cu atom resides on an inversion center and is bonded to the ligand through the pyridine N and the carbonyl O atoms [1.986(2) {\AA}], with a bite angle of 81.39(10)°. The thiophene is not involved in coordination. The coordinated water molecules are hydrogen bridged to adjacent BF4- anions, linking the cation and anion in an extended chain.",

author = "Sommerer, {Shaun O.} and Friebe, {Timothy L.} and Jircitano, {Alan J.} and Macbeth, {Cora E.} and Abboud, {Khalil A.}",

year = "1998",

month = feb,

day = "15",

doi = "10.1107/S0108270197014728",

language = "English (US)",

volume = "54",

pages = "178--179",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "2",

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TY - JOUR

T1 - trans-diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) tetrafluoroborate

AU - Sommerer, Shaun O.

AU - Friebe, Timothy L.

AU - Jircitano, Alan J.

AU - Macbeth, Cora E.

AU - Abboud, Khalil A.

PY - 1998/2/15

Y1 - 1998/2/15

N2 - The title complex, [Cu(C10H7NOS)2(H2O) 2](BF4)2, contains tetragonally elongated octahedral diaquabis(2-thienyl 2-pyridyl ketone)copper(II) cations counterbalanced with BF4- anions. The Cu atom resides on an inversion center and is bonded to the ligand through the pyridine N and the carbonyl O atoms [1.986(2) Å], with a bite angle of 81.39(10)°. The thiophene is not involved in coordination. The coordinated water molecules are hydrogen bridged to adjacent BF4- anions, linking the cation and anion in an extended chain.

AB - The title complex, [Cu(C10H7NOS)2(H2O) 2](BF4)2, contains tetragonally elongated octahedral diaquabis(2-thienyl 2-pyridyl ketone)copper(II) cations counterbalanced with BF4- anions. The Cu atom resides on an inversion center and is bonded to the ligand through the pyridine N and the carbonyl O atoms [1.986(2) Å], with a bite angle of 81.39(10)°. The thiophene is not involved in coordination. The coordinated water molecules are hydrogen bridged to adjacent BF4- anions, linking the cation and anion in an extended chain.

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SN - 0108-2701

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

trans-diaquabis(2-thienyl 2-pyridyl ketone-O,N)copper(II) tetrafluoroborate

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