TY - JOUR
T1 - Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II)
AU - Lerach, Jordan O.
AU - Zeller, Matthias
AU - Leskiw, Brian D.
PY - 2007/10/5
Y1 - 2007/10/5
N2 - The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octa-hedral geometry. The bidentate acetyl-acetonate-like ligands are in a trans arrangement. The plane through the acetyl-acetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydr-oxy groups, each mol-ecule participates in two pairs of inter-molecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.
AB - The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octa-hedral geometry. The bidentate acetyl-acetonate-like ligands are in a trans arrangement. The plane through the acetyl-acetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydr-oxy groups, each mol-ecule participates in two pairs of inter-molecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.
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U2 - 10.1107/S1600536807044340
DO - 10.1107/S1600536807044340
M3 - Article
AN - SCOPUS:35948938500
SN - 1600-5368
VL - 63
SP - m2639
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 11
ER -