Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II)

Jordan O. Lerach; Matthias Zeller; Brian D. Leskiw

doi:10.1107/S1600536807044340

Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II)

Jordan O. Lerach
, Matthias Zeller
, Brian D. Leskiw

Materials Research Institute (MRI)

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octa-hedral geometry. The bidentate acetyl-acetonate-like ligands are in a trans arrangement. The plane through the acetyl-acetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydr-oxy groups, each mol-ecule participates in two pairs of inter-molecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.

Original language	English (US)
Pages (from-to)	m2639
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	11
DOIs	https://doi.org/10.1107/S1600536807044340
State	Published - Oct 5 2007

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II)",

abstract = "The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octa-hedral geometry. The bidentate acetyl-acetonate-like ligands are in a trans arrangement. The plane through the acetyl-acetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydr-oxy groups, each mol-ecule participates in two pairs of inter-molecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.",

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T1 - Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II)

AU - Lerach, Jordan O.

AU - Zeller, Matthias

AU - Leskiw, Brian D.

PY - 2007/10/5

Y1 - 2007/10/5

N2 - The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octa-hedral geometry. The bidentate acetyl-acetonate-like ligands are in a trans arrangement. The plane through the acetyl-acetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydr-oxy groups, each mol-ecule participates in two pairs of inter-molecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.

AB - The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octa-hedral geometry. The bidentate acetyl-acetonate-like ligands are in a trans arrangement. The plane through the acetyl-acetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydr-oxy groups, each mol-ecule participates in two pairs of inter-molecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.

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DO - 10.1107/S1600536807044340

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato) cobalt(II)

Abstract

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