Transition metal phthalocyanine and porphyrin complexes as catalysts for the polymerization of alkenes

G. S. Long; B. Snedeker; K. Bartosh; M. L. Werner; A. Sen

doi:10.1139/v01-079

Transition metal phthalocyanine and porphyrin complexes as catalysts for the polymerization of alkenes

G. S. Long, B. Snedeker, K. Bartosh, M. L. Werner, A. Sen

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11 Scopus citations

Abstract

Vanadium phthalocyanine and porphyrin complexes, in conjunction with methylaluminoxane (MAO) or EtAlCl₂ cocatalyst, have been found to catalyze the homopolymerization of ethene. In addition, the copolymerization of ethene with propene and 1-decene was achieved with the vanadium phthalocyanine complex and MAO. Nickel phthalocyanine complex was also found to catalyze the polymerization of ethene in the presence of MAO. However, only dimerization was observed when EtAlCl₂ was used as the cocatalyst.

Original language	English (US)
Pages (from-to)	1026-1029
Number of pages	4
Journal	Canadian Journal of Chemistry
Volume	79
Issue number	5-6
DOIs	https://doi.org/10.1139/v01-079
State	Published - 2001

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Organic Chemistry

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abstract = "Vanadium phthalocyanine and porphyrin complexes, in conjunction with methylaluminoxane (MAO) or EtAlCl2 cocatalyst, have been found to catalyze the homopolymerization of ethene. In addition, the copolymerization of ethene with propene and 1-decene was achieved with the vanadium phthalocyanine complex and MAO. Nickel phthalocyanine complex was also found to catalyze the polymerization of ethene in the presence of MAO. However, only dimerization was observed when EtAlCl2 was used as the cocatalyst.",

author = "Long, {G. S.} and B. Snedeker and K. Bartosh and Werner, {M. L.} and A. Sen",

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journal = "Canadian Journal of Chemistry",

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T1 - Transition metal phthalocyanine and porphyrin complexes as catalysts for the polymerization of alkenes

AU - Long, G. S.

AU - Snedeker, B.

AU - Bartosh, K.

AU - Werner, M. L.

AU - Sen, A.

PY - 2001

Y1 - 2001

N2 - Vanadium phthalocyanine and porphyrin complexes, in conjunction with methylaluminoxane (MAO) or EtAlCl2 cocatalyst, have been found to catalyze the homopolymerization of ethene. In addition, the copolymerization of ethene with propene and 1-decene was achieved with the vanadium phthalocyanine complex and MAO. Nickel phthalocyanine complex was also found to catalyze the polymerization of ethene in the presence of MAO. However, only dimerization was observed when EtAlCl2 was used as the cocatalyst.

AB - Vanadium phthalocyanine and porphyrin complexes, in conjunction with methylaluminoxane (MAO) or EtAlCl2 cocatalyst, have been found to catalyze the homopolymerization of ethene. In addition, the copolymerization of ethene with propene and 1-decene was achieved with the vanadium phthalocyanine complex and MAO. Nickel phthalocyanine complex was also found to catalyze the polymerization of ethene in the presence of MAO. However, only dimerization was observed when EtAlCl2 was used as the cocatalyst.

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Transition metal phthalocyanine and porphyrin complexes as catalysts for the polymerization of alkenes

Abstract

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