Transition Metal Promoted Intramolecular Cyclizations of a, a-Dichloro Esters and Acids

Thomas K. Hayes; Alan J. Freyer; M. Parvez; Steven M. Weinreb

doi:10.1021/jo00376a109

Transition Metal Promoted Intramolecular Cyclizations of a, a-Dichloro Esters and Acids

Thomas K. Hayes, Alan J. Freyer, M. Parvez, Steven M. Weinreb

Chemistry

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Carbocyclic α, γ-dichloro esters or annulated a-chloro γ-lactones can be selectively synthesized via a radical process starting from olefinic a, a-dichloro esters and acids by appropriate choice of transition-metal catalyst and substrate.

Original language	English (US)
Pages (from-to)	5501-5503
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	51
Issue number	26
DOIs	https://doi.org/10.1021/jo00376a109
State	Published - 1986

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1021/jo00376a109

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@article{c9f3cdc82c6c4a4c9bb8b18bb0bf2520,

title = "Transition Metal Promoted Intramolecular Cyclizations of a, a-Dichloro Esters and Acids",

abstract = "Carbocyclic α, γ-dichloro esters or annulated a-chloro γ-lactones can be selectively synthesized via a radical process starting from olefinic a, a-dichloro esters and acids by appropriate choice of transition-metal catalyst and substrate.",

author = "Hayes, {Thomas K.} and Freyer, {Alan J.} and M. Parvez and Weinreb, {Steven M.}",

year = "1986",

doi = "10.1021/jo00376a109",

language = "English (US)",

volume = "51",

pages = "5501--5503",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "26",

}

TY - JOUR

T1 - Transition Metal Promoted Intramolecular Cyclizations of a, a-Dichloro Esters and Acids

AU - Hayes, Thomas K.

AU - Freyer, Alan J.

AU - Parvez, M.

AU - Weinreb, Steven M.

PY - 1986

Y1 - 1986

N2 - Carbocyclic α, γ-dichloro esters or annulated a-chloro γ-lactones can be selectively synthesized via a radical process starting from olefinic a, a-dichloro esters and acids by appropriate choice of transition-metal catalyst and substrate.

AB - Carbocyclic α, γ-dichloro esters or annulated a-chloro γ-lactones can be selectively synthesized via a radical process starting from olefinic a, a-dichloro esters and acids by appropriate choice of transition-metal catalyst and substrate.

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U2 - 10.1021/jo00376a109

DO - 10.1021/jo00376a109

M3 - Article

AN - SCOPUS:33845375895

SN - 0022-3263

VL - 51

SP - 5501

EP - 5503

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 26

ER -

Transition Metal Promoted Intramolecular Cyclizations of a, a-Dichloro Esters and Acids

Abstract

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