Trapping site geometry of N2H4+ radical ion in x-irradiated single crystals of N2H5HC 2O4: An ENDOR study

E. Sagstuen; O. Awadelkarim; A. Lund; J. Masiakowski

doi:10.1063/1.450991

Trapping site geometry of N₂H₄⁺ radical ion in x-irradiated single crystals of N₂H₅HC ₂O₄: An ENDOR study

E. Sagstuen, O. Awadelkarim, A. Lund, J. Masiakowski

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12 Scopus citations

Abstract

The radical ion N₂H₄⁺ has been produced by x irradiating single crystals of hydrazinium hydrogen oxalate (N ₂H₅HC₂O₄) and studied by ESR and ENDOR spectroscopy. The structure of the trapping site has been elucidated by observing ¹H ENDOR transitions not only from the radical but also from distant protons. One of the latter originates from the proton lost by N₂H₅⁺ upon radical formation. Evidence that proton transfer occurs through a hydrogen bond is presented.

Original language	English (US)
Pages (from-to)	3223-3228
Number of pages	6
Journal	The Journal of chemical physics
Volume	85
Issue number	6
DOIs	https://doi.org/10.1063/1.450991
State	Published - 1986

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.450991

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title = "Trapping site geometry of N2H4+ radical ion in x-irradiated single crystals of N2H5HC 2O4: An ENDOR study",

abstract = "The radical ion N2H4+ has been produced by x irradiating single crystals of hydrazinium hydrogen oxalate (N 2H5HC2O4) and studied by ESR and ENDOR spectroscopy. The structure of the trapping site has been elucidated by observing 1H ENDOR transitions not only from the radical but also from distant protons. One of the latter originates from the proton lost by N2H5+ upon radical formation. Evidence that proton transfer occurs through a hydrogen bond is presented.",

author = "E. Sagstuen and O. Awadelkarim and A. Lund and J. Masiakowski",

year = "1986",

doi = "10.1063/1.450991",

language = "English (US)",

volume = "85",

pages = "3223--3228",

journal = "The Journal of chemical physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "6",

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TY - JOUR

T1 - Trapping site geometry of N2H4+ radical ion in x-irradiated single crystals of N2H5HC 2O4

T2 - An ENDOR study

AU - Sagstuen, E.

AU - Awadelkarim, O.

AU - Lund, A.

AU - Masiakowski, J.

PY - 1986

Y1 - 1986

N2 - The radical ion N2H4+ has been produced by x irradiating single crystals of hydrazinium hydrogen oxalate (N 2H5HC2O4) and studied by ESR and ENDOR spectroscopy. The structure of the trapping site has been elucidated by observing 1H ENDOR transitions not only from the radical but also from distant protons. One of the latter originates from the proton lost by N2H5+ upon radical formation. Evidence that proton transfer occurs through a hydrogen bond is presented.

AB - The radical ion N2H4+ has been produced by x irradiating single crystals of hydrazinium hydrogen oxalate (N 2H5HC2O4) and studied by ESR and ENDOR spectroscopy. The structure of the trapping site has been elucidated by observing 1H ENDOR transitions not only from the radical but also from distant protons. One of the latter originates from the proton lost by N2H5+ upon radical formation. Evidence that proton transfer occurs through a hydrogen bond is presented.

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JO - The Journal of chemical physics

JF - The Journal of chemical physics

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ER -

Trapping site geometry of N₂H₄⁺ radical ion in x-irradiated single crystals of N₂H₅HC ₂O₄: An ENDOR study

Abstract

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