TY - JOUR

T1 - Using a mathematical model of a weathering clast to explore the effects of curvature on weathering

AU - Lebedeva, M. I.

AU - Sak, P. B.

AU - Ma, L.

AU - Brantley, S. L.

N1 - Funding Information:
This work was funded by the U.S. Department of Energy Office of Basic Sciences grant DE-FG02-OSER15675 to SLB. LM and PBS acknowledge partial funding from the National Science Foundation grants EAR-1251952 and EAR-1251969 .
Publisher Copyright:
© 2015.

PY - 2015/5/6

Y1 - 2015/5/6

N2 - For the first time, we show that rind thicknesses developed on surfaces of a clast with different values of curvature can be used to estimate the duration of clast weathering. To obtain an analytical expression for the velocity of the curvilinear weathering front on a clast of arbitrary shape, we approximate our previous multi-mineral reactive-diffusion model and explore a simplified 2-D model numerically and analytically.Our analysis documents that with increasing curvature of the weathering front, the mathematical description of weathering advance is equivalent to that derived for advection as the dominant solute transport mechanism, even for the case where transport is occurring by diffusion only. Specifically, for a curvilinear weathering front with constant curvature K<0, diffusivity (D), and porosity (ϕ), the normal component of the weathering advance rate can be calculated using an advection-like term where the advection velocity v can be expressed as v=Dϕ|K|. Therefore, at points along the rind-core interface with K<0, rind thickness is directly proportional to the absolute value of the curvature of the core-rind interface. The reaction front thickness also increases with K. These inferences are in agreement with field observations. This quantitative analysis allows an assessment of the duration of weathering if certain parameters are known. For example, using the difference in curvature observed at two positions for a clast that weathered in Guadeloupe (0.12mm-1 and 0.018mm-1) and the corresponding rind thickness difference (35.8mm and 20.6mm), we estimated the duration of weathering to be about 118ky, which is consistent with the weathering ages previously determined by U-series isotope disequilibrium.

AB - For the first time, we show that rind thicknesses developed on surfaces of a clast with different values of curvature can be used to estimate the duration of clast weathering. To obtain an analytical expression for the velocity of the curvilinear weathering front on a clast of arbitrary shape, we approximate our previous multi-mineral reactive-diffusion model and explore a simplified 2-D model numerically and analytically.Our analysis documents that with increasing curvature of the weathering front, the mathematical description of weathering advance is equivalent to that derived for advection as the dominant solute transport mechanism, even for the case where transport is occurring by diffusion only. Specifically, for a curvilinear weathering front with constant curvature K<0, diffusivity (D), and porosity (ϕ), the normal component of the weathering advance rate can be calculated using an advection-like term where the advection velocity v can be expressed as v=Dϕ|K|. Therefore, at points along the rind-core interface with K<0, rind thickness is directly proportional to the absolute value of the curvature of the core-rind interface. The reaction front thickness also increases with K. These inferences are in agreement with field observations. This quantitative analysis allows an assessment of the duration of weathering if certain parameters are known. For example, using the difference in curvature observed at two positions for a clast that weathered in Guadeloupe (0.12mm-1 and 0.018mm-1) and the corresponding rind thickness difference (35.8mm and 20.6mm), we estimated the duration of weathering to be about 118ky, which is consistent with the weathering ages previously determined by U-series isotope disequilibrium.

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U2 - 10.1016/j.chemgeo.2015.03.027

DO - 10.1016/j.chemgeo.2015.03.027

M3 - Article

AN - SCOPUS:84927597606

SN - 0009-2541

VL - 404

SP - 88

EP - 99

JO - Chemical Geology

JF - Chemical Geology

ER -