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Utilization of direct and diffuse sunlight in a dye-sensitized solar cell - Silicon photovoltaic hybrid concentrator system

  • Greg D. Barber
  • , Paul G. Hoertz
  • , Seung Hyun Anna Lee
  • , Neal M. Abrams
  • , Janine Mikulca
  • , Thomas E. Mallouk
  • , Paul Liska
  • , Shaik M. Zakeeruddin
  • , Michael Grätzel
  • , Anita Ho-Baillie
  • , Martin A. Green

Research output: Contribution to journalArticlepeer-review

Abstract

The concept of a tandem hybrid concentrator solar module was demonstrated from a dye-sensitized TiO2 solar cell (DSSCs) and a silicon p-n junction solar cell. The test system employed DSSC and Si cells with indoor AM1.5G efficiencies of 9.1 and 18.1%, respectively. Two different optical filters were used to selectively reflect and concentrate near-infrared light from the DSSC onto the Si cell. On the basis of outdoor testing in a 2× concentrator-reflector arrangement, the tandem system generated 93 and 96% of the output power of directly illuminated Si cells under altostratus/cirrostratus and clear sky irradiances, respectively, despite a DSSC-to-Si active area ratio of only 0.92. Similar performance is expected at higher (5-10×) concentration ratios. The hybrid arrangement of visible- and IR-absorbing solar cells addresses the problem of lower performance of conventional concentrators under diffuse irradiance conditions. These proof-of-concept results suggest that system level efficiencies approaching 20% should be achievable.

Original languageEnglish (US)
Pages (from-to)581-585
Number of pages5
JournalJournal of Physical Chemistry Letters
Volume2
Issue number6
DOIs
StatePublished - Mar 17 2011

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

All Science Journal Classification (ASJC) codes

  • General Materials Science
  • Physical and Theoretical Chemistry

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