Abstract
A constitutive equation is proposed for the viscoelastic diffusion flux, and this equation is used to calculate sorption curves for differential step-change sorption experiments. The predictions of the theory are shown to be consistent with eight experimental observations that report a wide range of diffusional behaviors for polymer-solvent systems.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1529-1547 |
| Number of pages | 19 |
| Journal | Journal of Polymer Science, Part B: Polymer Physics |
| Volume | 39 |
| Issue number | 13 |
| DOIs | |
| State | Published - Jul 1 2001 |
All Science Journal Classification (ASJC) codes
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Polymers and Plastics
- Materials Chemistry
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