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When gold and silver differ: interactions of N-heterocyclic carbenes with noble metal surfaces

  • Aruna Chandran
  • , Shayanta Chowdhury
  • , Gurkiran Kaur
  • , Gaohe Hu
  • , Nathaniel L. Dominique
  • , Lasse Jensen
  • , David M. Jenkins
  • , Jon P. Camden

Research output: Contribution to journalArticlepeer-review

Abstract

N-heterocyclic carbenes have transformed gold surface chemistry, but conventional deposition methods do not always translate effectively to silver substrates. We introduce a benchtop protocol that yields comparable monolayers on both metals, but also etches silver during the process. Controls show that oxygen is essential in both monolayer formation and substrate etching.

Original languageEnglish (US)
Pages (from-to)3269-3273
Number of pages5
JournalChemical Communications
Volume62
Issue number10
DOIs
StatePublished - Feb 5 2026

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Catalysis
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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