X-ray photoemission studies of atom implanted matrices: Cu, Ag, and Au in SiO2

V. Y. Young; R. A. Gibbs; N. Winograd

doi:10.1063/1.437450

X-ray photoemission studies of atom implanted matrices: Cu, Ag, and Au in SiO₂

V. Y. Young, R. A. Gibbs, N. Winograd

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Abstract

X-ray photoelectron spectroscopy has been used to study the electronic structure of Cu,Ag, and Au atoms implanted in SiO₂. In each case the valence levels shifted to higher binding energy and narrowed compared to the bulk metals, approaching the expected shape of the gas phase free atom spectra. A model is presented which allows calculation of photoemission and Auger energies from atomic spectra, and is shown to accurately predict the observed spectra.

Original language	English (US)
Pages (from-to)	5714-5721
Number of pages	8
Journal	The Journal of chemical physics
Volume	70
Issue number	12
DOIs	https://doi.org/10.1063/1.437450
State	Published - 1979

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.437450

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title = "X-ray photoemission studies of atom implanted matrices: Cu, Ag, and Au in SiO2",

abstract = "X-ray photoelectron spectroscopy has been used to study the electronic structure of Cu,Ag, and Au atoms implanted in SiO2. In each case the valence levels shifted to higher binding energy and narrowed compared to the bulk metals, approaching the expected shape of the gas phase free atom spectra. A model is presented which allows calculation of photoemission and Auger energies from atomic spectra, and is shown to accurately predict the observed spectra.",

author = "Young, {V. Y.} and Gibbs, {R. A.} and N. Winograd",

year = "1979",

doi = "10.1063/1.437450",

language = "English (US)",

volume = "70",

pages = "5714--5721",

journal = "The Journal of chemical physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

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TY - JOUR

T1 - X-ray photoemission studies of atom implanted matrices

T2 - Cu, Ag, and Au in SiO2

AU - Young, V. Y.

AU - Gibbs, R. A.

AU - Winograd, N.

PY - 1979

Y1 - 1979

N2 - X-ray photoelectron spectroscopy has been used to study the electronic structure of Cu,Ag, and Au atoms implanted in SiO2. In each case the valence levels shifted to higher binding energy and narrowed compared to the bulk metals, approaching the expected shape of the gas phase free atom spectra. A model is presented which allows calculation of photoemission and Auger energies from atomic spectra, and is shown to accurately predict the observed spectra.

AB - X-ray photoelectron spectroscopy has been used to study the electronic structure of Cu,Ag, and Au atoms implanted in SiO2. In each case the valence levels shifted to higher binding energy and narrowed compared to the bulk metals, approaching the expected shape of the gas phase free atom spectra. A model is presented which allows calculation of photoemission and Auger energies from atomic spectra, and is shown to accurately predict the observed spectra.

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U2 - 10.1063/1.437450

DO - 10.1063/1.437450

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JO - The Journal of chemical physics

JF - The Journal of chemical physics

IS - 12

ER -

X-ray photoemission studies of atom implanted matrices: Cu, Ag, and Au in SiO₂

Abstract

All Science Journal Classification (ASJC) codes

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