Abstract
A ZnIn2S4/g-C3N4 heterojunction–enabled dual-mode photoelectrochemical–electrochemiluminescent (PEC–ECL) biosensor was constructed for the quenching detection of fipronil, in which the inputs of the target fipronil triggered double-step catalytic hairpin assembly (CHA) circuits, leading to the introduction of a MnO2 nanoflower (NF) quencher. Leveraging the excellent changes in the signals, this biosensor exhibited a wide linear range with a detection limit of 6.8 fM in PEC mode and 6.2 fM in ECL mode. Furthermore, it allowed for fipronil analysis in lettuce and egg samples, exhibiting excellent consistency with the standard method, which confirmed its potential for food safety monitoring.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 4615-4618 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 62 |
| Issue number | 15 |
| DOIs | |
| State | Published - Feb 24 2026 |
All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Catalysis
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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