ZSM-5 zeolite/porous carbon composite: Conventional- and microwave-hydrothermal synthesis from carbonized rice husk

Hiroaki Katsuki; Sachiko Furuta; Takanori Watari; Sridhar Komarneni

doi:10.1016/j.micromeso.2005.07.010

ZSM-5 zeolite/porous carbon composite: Conventional- and microwave-hydrothermal synthesis from carbonized rice husk

Hiroaki Katsuki, Sachiko Furuta, Takanori Watari, Sridhar Komarneni

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

The formation of novel ZSM-5 zeolite/porous carbon composite from carbonized rice husk has been investigated using microwave- and conventional-hydrothermal reaction at 140-160 °C. ZSM-5 zeolite crystals were formed on porous carbonized rice husk by the dissolution and in situ crystallization of silica in the carbonized rice husk. Compared to the conventional-hydrothermal (C-H) formation of ZSM-5 zeolite, the microwave-hydrothermal (M-H) reaction led to increased rate of formation by 3-4 times at 150 °C. In addition M-H reaction yielded small particles of 0.3-5 μm. The surface area of ZSM-5 zeolite (without template)/porous carbon composite is 485.4 m²/g, and this composite has both micropores and mesopores.

Original language	English (US)
Pages (from-to)	145-151
Number of pages	7
Journal	Microporous and Mesoporous Materials
Volume	86
Issue number	1-3
DOIs	https://doi.org/10.1016/j.micromeso.2005.07.010
State	Published - Nov 28 2005

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials

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10.1016/j.micromeso.2005.07.010

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title = "ZSM-5 zeolite/porous carbon composite: Conventional- and microwave-hydrothermal synthesis from carbonized rice husk",

abstract = "The formation of novel ZSM-5 zeolite/porous carbon composite from carbonized rice husk has been investigated using microwave- and conventional-hydrothermal reaction at 140-160 °C. ZSM-5 zeolite crystals were formed on porous carbonized rice husk by the dissolution and in situ crystallization of silica in the carbonized rice husk. Compared to the conventional-hydrothermal (C-H) formation of ZSM-5 zeolite, the microwave-hydrothermal (M-H) reaction led to increased rate of formation by 3-4 times at 150 °C. In addition M-H reaction yielded small particles of 0.3-5 μm. The surface area of ZSM-5 zeolite (without template)/porous carbon composite is 485.4 m2/g, and this composite has both micropores and mesopores.",

author = "Hiroaki Katsuki and Sachiko Furuta and Takanori Watari and Sridhar Komarneni",

year = "2005",

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doi = "10.1016/j.micromeso.2005.07.010",

language = "English (US)",

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T1 - ZSM-5 zeolite/porous carbon composite

T2 - Conventional- and microwave-hydrothermal synthesis from carbonized rice husk

AU - Katsuki, Hiroaki

AU - Furuta, Sachiko

AU - Watari, Takanori

AU - Komarneni, Sridhar

PY - 2005/11/28

Y1 - 2005/11/28

N2 - The formation of novel ZSM-5 zeolite/porous carbon composite from carbonized rice husk has been investigated using microwave- and conventional-hydrothermal reaction at 140-160 °C. ZSM-5 zeolite crystals were formed on porous carbonized rice husk by the dissolution and in situ crystallization of silica in the carbonized rice husk. Compared to the conventional-hydrothermal (C-H) formation of ZSM-5 zeolite, the microwave-hydrothermal (M-H) reaction led to increased rate of formation by 3-4 times at 150 °C. In addition M-H reaction yielded small particles of 0.3-5 μm. The surface area of ZSM-5 zeolite (without template)/porous carbon composite is 485.4 m2/g, and this composite has both micropores and mesopores.

AB - The formation of novel ZSM-5 zeolite/porous carbon composite from carbonized rice husk has been investigated using microwave- and conventional-hydrothermal reaction at 140-160 °C. ZSM-5 zeolite crystals were formed on porous carbonized rice husk by the dissolution and in situ crystallization of silica in the carbonized rice husk. Compared to the conventional-hydrothermal (C-H) formation of ZSM-5 zeolite, the microwave-hydrothermal (M-H) reaction led to increased rate of formation by 3-4 times at 150 °C. In addition M-H reaction yielded small particles of 0.3-5 μm. The surface area of ZSM-5 zeolite (without template)/porous carbon composite is 485.4 m2/g, and this composite has both micropores and mesopores.

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DO - 10.1016/j.micromeso.2005.07.010

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SN - 1387-1811

VL - 86

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JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

ZSM-5 zeolite/porous carbon composite: Conventional- and microwave-hydrothermal synthesis from carbonized rice husk

Abstract

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