Zwitterionic polymerization of lactide to cyclic poly(lactide) by using N-heterocyclic carbene organocatalysts

Darcy A. Culkin; Wonhee Jeong; Szilárd Csihony; Enrique D. Gomez; Nitash P. Balsara; James L. Hedrick; Robert M. Waymouth

doi:10.1002/anie.200604740

Zwitterionic polymerization of lactide to cyclic poly(lactide) by using N-heterocyclic carbene organocatalysts

Darcy A. Culkin
, Wonhee Jeong
, Szilárd Csihony
, Enrique D. Gomez
, Nitash P. Balsara
, James L. Hedrick
, Robert M. Waymouth

Research output: Contribution to journal › Article › peer-review

361 Scopus citations

Abstract

(Chemical Equation Presented) Closing the loop: The zwitterionic ring-opening polymerization of lactide in the presence of N-heterocyclic carbenes generates well-defined cyclic poly(lactide) (see scheme). The polymerization is rapid and produces macrocyclic polymers with high purity and exceptional control of molecular weight and polydispersity.

Original language	English (US)
Pages (from-to)	2627-2630
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	15
DOIs	https://doi.org/10.1002/anie.200604740
State	Published - 2007

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

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10.1002/anie.200604740

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abstract = "(Chemical Equation Presented) Closing the loop: The zwitterionic ring-opening polymerization of lactide in the presence of N-heterocyclic carbenes generates well-defined cyclic poly(lactide) (see scheme). The polymerization is rapid and produces macrocyclic polymers with high purity and exceptional control of molecular weight and polydispersity.",

author = "Culkin, \{Darcy A.\} and Wonhee Jeong and Szil{\'a}rd Csihony and Gomez, \{Enrique D.\} and Balsara, \{Nitash P.\} and Hedrick, \{James L.\} and Waymouth, \{Robert M.\}",

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AU - Culkin, Darcy A.

AU - Jeong, Wonhee

AU - Csihony, Szilárd

AU - Gomez, Enrique D.

AU - Balsara, Nitash P.

AU - Hedrick, James L.

AU - Waymouth, Robert M.

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) Closing the loop: The zwitterionic ring-opening polymerization of lactide in the presence of N-heterocyclic carbenes generates well-defined cyclic poly(lactide) (see scheme). The polymerization is rapid and produces macrocyclic polymers with high purity and exceptional control of molecular weight and polydispersity.

AB - (Chemical Equation Presented) Closing the loop: The zwitterionic ring-opening polymerization of lactide in the presence of N-heterocyclic carbenes generates well-defined cyclic poly(lactide) (see scheme). The polymerization is rapid and produces macrocyclic polymers with high purity and exceptional control of molecular weight and polydispersity.

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M3 - Article

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AN - SCOPUS:34250849662

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Zwitterionic polymerization of lactide to cyclic poly(lactide) by using N-heterocyclic carbene organocatalysts

Abstract

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